Syntheses and characterization of N,N′-dipropyl/diisopropylethane-1,2-diamine complexes of nickel(II) nitrate: Thermal studies and X-ray single crystal structure analysis of cis-nitratobis (N,N′-dipropylethane-1,2-diamine)nickel(II) nitrate

Inamur Rahaman Laskar; Debasis Das; Nirmalendu Ray Chaudhuri; Golam Mostafa; Alan J. Welch

Syntheses and characterization of N,N′-dipropyl/diisopropylethane-1,2-diamine complexes of nickel(II) nitrate: Thermal studies and X-ray single crystal structure analysis of cis-nitratobis (N,N′-dipropylethane-1,2-diamine)nickel(II) nitrate

Inamur Rahaman Laskar
, Debasis Das
, Nirmalendu Ray Chaudhuri
, Golam Mostafa
, Alan J. Welch

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The blue complex cis-[Ni(dipren)₂(NO₃)](NO₃) 1 and the greenish blue cis-[Ni(dipren)₂ (H₂O)₂](NO₃)₂ · 2H₂O 2 (dpren/dpren = dipropyl/diisopropylethane-1,2-diamine) have been synthesized. Complex 2 upon heating loses four water molecules in a single step and undergoes melting accompanied with colour change, greenish blue to deep green, 2a. Configuration of the complexes 1,2 and 2a have been proposed to be cis-octahedral on the basis of magnetic, IR and electronic spectroscopic studies and confirmed in case of complex 1 by X-ray single crystal structure analysis. The role of steric factor of the alkyl groups on the selectivity of coordinating mode of nitrate ion is studied. © 1998 Elsevier Science Ltd. All rights reserved.

Original language	English
Pages (from-to)	1363-1368
Number of pages	6
Journal	Polyhedron
Volume	17
Issue number	8
Publication status	Published - 30 Apr 1998

Keywords

Cis-octahedral geometry of nickel(II)
N,N′-diisopropylethane-1,2-diamine
N,N′-dipropylethane-1,2-diamine
Nickel(II) diamine complex
Nitratobis(N,N′-dipropylethane-1,2-diamine)nickel(II) nitrate
Thermochromism

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Laskar, Inamur Rahaman ; Das, Debasis ; Chaudhuri, Nirmalendu Ray et al. / Syntheses and characterization of N,N′-dipropyl/diisopropylethane-1,2-diamine complexes of nickel(II) nitrate : Thermal studies and X-ray single crystal structure analysis of cis-nitratobis (N,N′-dipropylethane-1,2-diamine)nickel(II) nitrate. In: Polyhedron. 1998 ; Vol. 17, No. 8. pp. 1363-1368.

@article{f9db6417d435490b993039499aceb7eb,

title = "Syntheses and characterization of N,N′-dipropyl/diisopropylethane-1,2-diamine complexes of nickel(II) nitrate: Thermal studies and X-ray single crystal structure analysis of cis-nitratobis (N,N′-dipropylethane-1,2-diamine)nickel(II) nitrate",

abstract = "The blue complex cis-[Ni(dipren)2(NO3)](NO3) 1 and the greenish blue cis-[Ni(dipren)2 (H2O)2](NO3)2 · 2H2O 2 (dpren/dpren = dipropyl/diisopropylethane-1,2-diamine) have been synthesized. Complex 2 upon heating loses four water molecules in a single step and undergoes melting accompanied with colour change, greenish blue to deep green, 2a. Configuration of the complexes 1,2 and 2a have been proposed to be cis-octahedral on the basis of magnetic, IR and electronic spectroscopic studies and confirmed in case of complex 1 by X-ray single crystal structure analysis. The role of steric factor of the alkyl groups on the selectivity of coordinating mode of nitrate ion is studied. {\textcopyright} 1998 Elsevier Science Ltd. All rights reserved.",

keywords = "Cis-octahedral geometry of nickel(II), N,N′-diisopropylethane-1,2-diamine, N,N′-dipropylethane-1,2-diamine, Nickel(II) diamine complex, Nitratobis(N,N′-dipropylethane-1,2-diamine)nickel(II) nitrate, Thermochromism",

author = "Laskar, \{Inamur Rahaman\} and Debasis Das and Chaudhuri, \{Nirmalendu Ray\} and Golam Mostafa and Welch, \{Alan J.\}",

year = "1998",

month = apr,

day = "30",

language = "English",

volume = "17",

pages = "1363--1368",

journal = "Polyhedron",

publisher = "Elsevier Ltd",

number = "8",

}

Syntheses and characterization of N,N′-dipropyl/diisopropylethane-1,2-diamine complexes of nickel(II) nitrate: Thermal studies and X-ray single crystal structure analysis of cis-nitratobis (N,N′-dipropylethane-1,2-diamine)nickel(II) nitrate. / Laskar, Inamur Rahaman; Das, Debasis; Chaudhuri, Nirmalendu Ray et al.
In: Polyhedron, Vol. 17, No. 8, 30.04.1998, p. 1363-1368.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Syntheses and characterization of N,N′-dipropyl/diisopropylethane-1,2-diamine complexes of nickel(II) nitrate

T2 - Thermal studies and X-ray single crystal structure analysis of cis-nitratobis (N,N′-dipropylethane-1,2-diamine)nickel(II) nitrate

AU - Laskar, Inamur Rahaman

AU - Das, Debasis

AU - Chaudhuri, Nirmalendu Ray

AU - Mostafa, Golam

AU - Welch, Alan J.

PY - 1998/4/30

Y1 - 1998/4/30

N2 - The blue complex cis-[Ni(dipren)2(NO3)](NO3) 1 and the greenish blue cis-[Ni(dipren)2 (H2O)2](NO3)2 · 2H2O 2 (dpren/dpren = dipropyl/diisopropylethane-1,2-diamine) have been synthesized. Complex 2 upon heating loses four water molecules in a single step and undergoes melting accompanied with colour change, greenish blue to deep green, 2a. Configuration of the complexes 1,2 and 2a have been proposed to be cis-octahedral on the basis of magnetic, IR and electronic spectroscopic studies and confirmed in case of complex 1 by X-ray single crystal structure analysis. The role of steric factor of the alkyl groups on the selectivity of coordinating mode of nitrate ion is studied. © 1998 Elsevier Science Ltd. All rights reserved.

AB - The blue complex cis-[Ni(dipren)2(NO3)](NO3) 1 and the greenish blue cis-[Ni(dipren)2 (H2O)2](NO3)2 · 2H2O 2 (dpren/dpren = dipropyl/diisopropylethane-1,2-diamine) have been synthesized. Complex 2 upon heating loses four water molecules in a single step and undergoes melting accompanied with colour change, greenish blue to deep green, 2a. Configuration of the complexes 1,2 and 2a have been proposed to be cis-octahedral on the basis of magnetic, IR and electronic spectroscopic studies and confirmed in case of complex 1 by X-ray single crystal structure analysis. The role of steric factor of the alkyl groups on the selectivity of coordinating mode of nitrate ion is studied. © 1998 Elsevier Science Ltd. All rights reserved.

KW - Cis-octahedral geometry of nickel(II)

KW - N,N′-diisopropylethane-1,2-diamine

KW - N,N′-dipropylethane-1,2-diamine

KW - Nickel(II) diamine complex

KW - Nitratobis(N,N′-dipropylethane-1,2-diamine)nickel(II) nitrate

KW - Thermochromism

M3 - Article

VL - 17

SP - 1363

EP - 1368

JO - Polyhedron

JF - Polyhedron

IS - 8

ER -