Supramolecular isomerism of a metallocyclic dipyridyldiamide ligand metal halide system generating isostructural (Hg, Co and Zn) porous materials

Christopher D Jones; Jin Chong Tan; Gareth O Lloyd

doi:10.1039/c2cc16691g

Supramolecular isomerism of a metallocyclic dipyridyldiamide ligand metal halide system generating isostructural (Hg, Co and Zn) porous materials

Christopher D Jones, Jin Chong Tan, Gareth O Lloyd

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

We show how crystallisation of supramolecular isomers of a dynamic coordination system generates a series of isostructural porous materials. These mercury, cobalt and zinc metallocyclic materials show permanent porosity and exhibit single-crystal-to-single-crystal transformations.

Original language	English
Pages (from-to)	2110-2112
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	15
DOIs	https://doi.org/10.1039/c2cc16691g
Publication status	Published - 2012

Keywords

ORGANIC FRAMEWORKS
COORDINATION NETWORKS
THERMAL-PROPERTIES
SINGLE-CRYSTAL
ANION-BINDING
HYDROGEN
POLYMERS
ADSORPTION
PHOTOLUMINESCENCE
POLYMORPHISM

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title = "Supramolecular isomerism of a metallocyclic dipyridyldiamide ligand metal halide system generating isostructural (Hg, Co and Zn) porous materials",

abstract = "We show how crystallisation of supramolecular isomers of a dynamic coordination system generates a series of isostructural porous materials. These mercury, cobalt and zinc metallocyclic materials show permanent porosity and exhibit single-crystal-to-single-crystal transformations.",

keywords = "ORGANIC FRAMEWORKS, COORDINATION NETWORKS, THERMAL-PROPERTIES, SINGLE-CRYSTAL, ANION-BINDING, HYDROGEN, POLYMERS, ADSORPTION, PHOTOLUMINESCENCE, POLYMORPHISM",

author = "Jones, {Christopher D} and Tan, {Jin Chong} and Lloyd, {Gareth O}",

year = "2012",

doi = "10.1039/c2cc16691g",

language = "English",

volume = "48",

pages = "2110--2112",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "15",

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T1 - Supramolecular isomerism of a metallocyclic dipyridyldiamide ligand metal halide system generating isostructural (Hg, Co and Zn) porous materials

AU - Jones, Christopher D

AU - Tan, Jin Chong

AU - Lloyd, Gareth O

PY - 2012

Y1 - 2012

N2 - We show how crystallisation of supramolecular isomers of a dynamic coordination system generates a series of isostructural porous materials. These mercury, cobalt and zinc metallocyclic materials show permanent porosity and exhibit single-crystal-to-single-crystal transformations.

AB - We show how crystallisation of supramolecular isomers of a dynamic coordination system generates a series of isostructural porous materials. These mercury, cobalt and zinc metallocyclic materials show permanent porosity and exhibit single-crystal-to-single-crystal transformations.

KW - ORGANIC FRAMEWORKS

KW - COORDINATION NETWORKS

KW - THERMAL-PROPERTIES

KW - SINGLE-CRYSTAL

KW - ANION-BINDING

KW - HYDROGEN

KW - POLYMERS

KW - ADSORPTION

KW - PHOTOLUMINESCENCE

KW - POLYMORPHISM

U2 - 10.1039/c2cc16691g

DO - 10.1039/c2cc16691g

M3 - Article

C2 - 22249905

SN - 1359-7345

VL - 48

SP - 2110

EP - 2112

JO - Chemical Communications

JF - Chemical Communications

IS - 15

ER -

Supramolecular isomerism of a metallocyclic dipyridyldiamide ligand metal halide system generating isostructural (Hg, Co and Zn) porous materials

Abstract

Keywords

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