Supramolecular assemblies of p-sulfonatocalix[4]arene with aquated trivalent lanthanide ions

Jerry L Atwood; Leonard J Barbour; Scott J Dalgarno; Colin L Raston; Helen R Webb

doi:10.1039/b206129e

Supramolecular assemblies of p-sulfonatocalix[4]arene with aquated trivalent lanthanide ions

Jerry L Atwood, Leonard J Barbour, Scott J Dalgarno, Colin L Raston, Helen R Webb

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60 Citations (Scopus)

Abstract

New structural motifs incorporating trivalent lanthanoid ions and p-sulfonatocalix[4]arene, derived from solutions with or without potential host molecules for the calixarene, notably 18-crown-6, 1-aza-18-crown-6, and cryptand[2.2.2], have been authenticated. These include coordination polymers which form bi-layer sheet structures and an unprecedented combined `ferris wheel' and `molecular capsule' structure for Ce(3+) which incorporates two previously reported structural motifs associated with this type of chemistry, respectively for elements to the left and right of cerium in the lanthanide series.

Original language	English
Pages (from-to)	4351-4356
Number of pages	6
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	23
DOIs	https://doi.org/10.1039/b206129e
Publication status	Published - 2002

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abstract = "New structural motifs incorporating trivalent lanthanoid ions and p-sulfonatocalix[4]arene, derived from solutions with or without potential host molecules for the calixarene, notably 18-crown-6, 1-aza-18-crown-6, and cryptand[2.2.2], have been authenticated. These include coordination polymers which form bi-layer sheet structures and an unprecedented combined `ferris wheel' and `molecular capsule' structure for Ce(3+) which incorporates two previously reported structural motifs associated with this type of chemistry, respectively for elements to the left and right of cerium in the lanthanide series.",

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AU - Atwood, Jerry L

AU - Barbour, Leonard J

AU - Dalgarno, Scott J

AU - Raston, Colin L

AU - Webb, Helen R

PY - 2002

Y1 - 2002

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AB - New structural motifs incorporating trivalent lanthanoid ions and p-sulfonatocalix[4]arene, derived from solutions with or without potential host molecules for the calixarene, notably 18-crown-6, 1-aza-18-crown-6, and cryptand[2.2.2], have been authenticated. These include coordination polymers which form bi-layer sheet structures and an unprecedented combined `ferris wheel' and `molecular capsule' structure for Ce(3+) which incorporates two previously reported structural motifs associated with this type of chemistry, respectively for elements to the left and right of cerium in the lanthanide series.

U2 - 10.1039/b206129e

DO - 10.1039/b206129e

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JF - Journal of the Chemical Society, Dalton Transactions

IS - 23

ER -

Supramolecular assemblies of p-sulfonatocalix[4]arene with aquated trivalent lanthanide ions

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