Sulfide scale control: A high efficacy breakthrough using an innovative class of polymeric inhibitors

Adam Justin Savin, Ben Adamson, Jonathan James Wylde, Jamie Richard Kerr, Christoph Wolfgang Kayser, Taina Trallenkamp, Dirk Fischer, Cyril Okocha

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    Abstract

    Prevention of sulfide scale through the use of chemistry is a developing area of focus within the oil industry. There are few examples of a single chemical approach working, where scale inhibitor species function at threshold concentrations. Partial inhibition may be provided by (standard' scale inhibitors using established chemistries such as phosphonates or polymeric species. However, the efficacy of these inhibitors against sulfide scale is generally poor and high concentrations are typically required. Based on an industry need for a true, high-performance sulfide scale inhibitor, work was undertaken to develop a novel chemistry that would offer a step-change in performance from existing technologies. Using a new advanced rapid screening technique, a wide range of (standard' scale inhibitors were assessed, which proved that the majority of these chemistries display no efficacy against sulfide scale. A select few of the standard scale inhibitors displayed limited efficacy and from this data common molecular features which contributed to sulfide scale inhibition were identified. Utilizing this knowledge, a range of novel polymeric chemistries were synthesized which provide significantly superior inhibition than any other postulated for this application. It has been possible to identify specific moieties within these complex polymers which are required for sulfide scale inhibition and to theorize on likely molecular structure-performance relationships for this new class of scale inhibitor. Additionally, hypotheses on the specific mechanisms by which these inhibitors function have been provided, showing why they are so successful at sulfide crystal growth retardation. Static and dynamic test methods are described that accurately mimic formation of these scales in the field, in comparing the novel polymeric chemistry with the best-performing (standard' scale inhibitors. Order of magnitude increases in performance over standard species are reported which represents a true step-change in the efficacy of sulfide scale inhibition.
    Original languageEnglish
    Title of host publicationSPE International Conference and Exhibition on Oilfield Scale 2014
    Place of PublicationRichardson, Texas
    PublisherSociety of Petroleum Engineers
    Pages381-394
    Number of pages14
    ISBN (Electronic)9781613993255
    ISBN (Print)9781632665911
    DOIs
    Publication statusPublished - 2014
    EventSPE International Oilfield Scale Conference and Exhibition - Aberdeen, United Kingdom
    Duration: 14 May 201415 May 2014

    Conference

    ConferenceSPE International Oilfield Scale Conference and Exhibition
    CountryUnited Kingdom
    CityAberdeen
    Period14/05/1415/05/14

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  • Cite this

    Savin, A. J., Adamson, B., Wylde, J. J., Kerr, J. R., Kayser, C. W., Trallenkamp, T., Fischer, D., & Okocha, C. (2014). Sulfide scale control: A high efficacy breakthrough using an innovative class of polymeric inhibitors. In SPE International Conference and Exhibition on Oilfield Scale 2014 (pp. 381-394). Society of Petroleum Engineers. https://doi.org/10.2118/169777-MS