Successful extrapolation of an f-element synthetic method to the pseudo light lanthanoid, aluminium

Jacinta M Bakker; Leonard J Barbour; Glen B Deacon; Peter C Junk; Gareth O Lloyd; Jonathan W Steed

doi:10.1016/j.jorganchem.2010.08.007

Successful extrapolation of an f-element synthetic method to the pseudo light lanthanoid, aluminium

Jacinta M Bakker, Leonard J Barbour, Glen B Deacon, Peter C Junk, Gareth O Lloyd, Jonathan W Steed

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

A redox transmetallation/ligand exchange reaction between Al metal, Hg(C6F5)(2) and 3,5-di-tert-butyl-pyrazole (tBu(2)pzH) in tetrahydrofuran (thf) yields [Al(tBu(2)pz)(3)(thf)] in which the six coordinate aluminium atom has two eta(2)- and one eta(1)-tBu(2)pz ligands. By contrast an analogous reaction in 1,2-dimethoxyethane (dme) gives the organoaluminium complex [Al-2(tBu(2)pz)(3)(C6F5)(2)(OCH2CH2OCH3)] in which each aluminium atom has an eta(2)-pyrazolate and a C6F5 ligand and the Al atoms are bridged by an eta(1):eta(1)-tBu(2)pz ligand and a 2-methoxyethoxide ligand. In addition, [Al(tBu(2)pz)(3)] was isolated from the reaction mixture in a different form from that previously reprinted. (c) 2010 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	2720-2725
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	695
Issue number	25-26
DOIs	https://doi.org/10.1016/j.jorganchem.2010.08.007
Publication status	Published - Dec 2010
Event	Organo-f-Element Chemistry at Pacifichem 2010 - Honolulu, Hawaii, United States Duration: 15 Dec 2010 → 20 Dec 2010

Keywords

Redox transmetallation/ligand exchange
Aluminium complexes
Pyrazole and pyrazolates
High Z'
Crystallography
BEARING ETA(2)-PYRAZOLATO LIGANDS
MOLECULAR-ORBITAL CALCULATIONS
PYRAZOLATE COORDINATION MODES
ARYLOXIDE COMPLEXES
CRYSTAL-STRUCTURES
MULTIPLE MOLECULES
ALUMOXANE HYDRIDE
EARTH-METAL
CHEMISTRY
REACTIVITY

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10.1016/j.jorganchem.2010.08.007

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@article{dee3f9d63c27422e965d53a187162d4a,

title = "Successful extrapolation of an f-element synthetic method to the pseudo light lanthanoid, aluminium",

abstract = "A redox transmetallation/ligand exchange reaction between Al metal, Hg(C6F5)(2) and 3,5-di-tert-butyl-pyrazole (tBu(2)pzH) in tetrahydrofuran (thf) yields [Al(tBu(2)pz)(3)(thf)] in which the six coordinate aluminium atom has two eta(2)- and one eta(1)-tBu(2)pz ligands. By contrast an analogous reaction in 1,2-dimethoxyethane (dme) gives the organoaluminium complex [Al-2(tBu(2)pz)(3)(C6F5)(2)(OCH2CH2OCH3)] in which each aluminium atom has an eta(2)-pyrazolate and a C6F5 ligand and the Al atoms are bridged by an eta(1):eta(1)-tBu(2)pz ligand and a 2-methoxyethoxide ligand. In addition, [Al(tBu(2)pz)(3)] was isolated from the reaction mixture in a different form from that previously reprinted. (c) 2010 Elsevier B.V. All rights reserved.",

keywords = "Redox transmetallation/ligand exchange, Aluminium complexes, Pyrazole and pyrazolates, High Z', Crystallography, BEARING ETA(2)-PYRAZOLATO LIGANDS, MOLECULAR-ORBITAL CALCULATIONS, PYRAZOLATE COORDINATION MODES, ARYLOXIDE COMPLEXES, CRYSTAL-STRUCTURES, MULTIPLE MOLECULES, ALUMOXANE HYDRIDE, EARTH-METAL, CHEMISTRY, REACTIVITY",

author = "Bakker, {Jacinta M} and Barbour, {Leonard J} and Deacon, {Glen B} and Junk, {Peter C} and Lloyd, {Gareth O} and Steed, {Jonathan W}",

year = "2010",

month = dec,

doi = "10.1016/j.jorganchem.2010.08.007",

language = "English",

volume = "695",

pages = "2720--2725",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "25-26",

note = "Organo-f-Element Chemistry at Pacifichem 2010 ; Conference date: 15-12-2010 Through 20-12-2010",

}

TY - JOUR

T1 - Successful extrapolation of an f-element synthetic method to the pseudo light lanthanoid, aluminium

AU - Bakker, Jacinta M

AU - Barbour, Leonard J

AU - Deacon, Glen B

AU - Junk, Peter C

AU - Lloyd, Gareth O

AU - Steed, Jonathan W

PY - 2010/12

Y1 - 2010/12

N2 - A redox transmetallation/ligand exchange reaction between Al metal, Hg(C6F5)(2) and 3,5-di-tert-butyl-pyrazole (tBu(2)pzH) in tetrahydrofuran (thf) yields [Al(tBu(2)pz)(3)(thf)] in which the six coordinate aluminium atom has two eta(2)- and one eta(1)-tBu(2)pz ligands. By contrast an analogous reaction in 1,2-dimethoxyethane (dme) gives the organoaluminium complex [Al-2(tBu(2)pz)(3)(C6F5)(2)(OCH2CH2OCH3)] in which each aluminium atom has an eta(2)-pyrazolate and a C6F5 ligand and the Al atoms are bridged by an eta(1):eta(1)-tBu(2)pz ligand and a 2-methoxyethoxide ligand. In addition, [Al(tBu(2)pz)(3)] was isolated from the reaction mixture in a different form from that previously reprinted. (c) 2010 Elsevier B.V. All rights reserved.

AB - A redox transmetallation/ligand exchange reaction between Al metal, Hg(C6F5)(2) and 3,5-di-tert-butyl-pyrazole (tBu(2)pzH) in tetrahydrofuran (thf) yields [Al(tBu(2)pz)(3)(thf)] in which the six coordinate aluminium atom has two eta(2)- and one eta(1)-tBu(2)pz ligands. By contrast an analogous reaction in 1,2-dimethoxyethane (dme) gives the organoaluminium complex [Al-2(tBu(2)pz)(3)(C6F5)(2)(OCH2CH2OCH3)] in which each aluminium atom has an eta(2)-pyrazolate and a C6F5 ligand and the Al atoms are bridged by an eta(1):eta(1)-tBu(2)pz ligand and a 2-methoxyethoxide ligand. In addition, [Al(tBu(2)pz)(3)] was isolated from the reaction mixture in a different form from that previously reprinted. (c) 2010 Elsevier B.V. All rights reserved.

KW - Redox transmetallation/ligand exchange

KW - Aluminium complexes

KW - Pyrazole and pyrazolates

KW - High Z'

KW - Crystallography

KW - BEARING ETA(2)-PYRAZOLATO LIGANDS

KW - MOLECULAR-ORBITAL CALCULATIONS

KW - PYRAZOLATE COORDINATION MODES

KW - ARYLOXIDE COMPLEXES

KW - CRYSTAL-STRUCTURES

KW - MULTIPLE MOLECULES

KW - ALUMOXANE HYDRIDE

KW - EARTH-METAL

KW - CHEMISTRY

KW - REACTIVITY

U2 - 10.1016/j.jorganchem.2010.08.007

DO - 10.1016/j.jorganchem.2010.08.007

M3 - Article

SN - 0022-328X

VL - 695

SP - 2720

EP - 2725

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 25-26

T2 - Organo-f-Element Chemistry at Pacifichem 2010

Y2 - 15 December 2010 through 20 December 2010

ER -

Successful extrapolation of an f-element synthetic method to the pseudo light lanthanoid, aluminium

Abstract

Keywords

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