Study of the dehydrochlorination of polyvinylidene chloride by alcoholic base, using ultra-violet absorption spectroscopy

Stuart S. Barton, Gordon Boulton, Brian H. Harrison, William Kemp

Research output: Contribution to journalArticle

Abstract

Carbonization of polyvinylidene chloride by base involves abstraction of hydrogen chloride. The present work on the ultra-violet absorption spectra of partially carbonized polymer shows that this occurs predominantly by way of each molecule, in succession, losing its hydrogen chloride rapidly along the chain length. The introduction of extensive unsaturation into one molecule occurs faster than the introduction of low degrees of unsaturation into several molecules.

Original languageEnglish
Pages (from-to)3534-3539
Number of pages6
JournalTransactions of the Faraday Society
Volume67
DOIs
Publication statusPublished - 1971

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Ultraviolet spectroscopy
Absorption spectroscopy
Hydrochloric Acid
Molecules
Carbonization
Chain length
Absorption spectra
Polymers
polyvinylidene chloride

Cite this

Barton, Stuart S. ; Boulton, Gordon ; Harrison, Brian H. ; Kemp, William. / Study of the dehydrochlorination of polyvinylidene chloride by alcoholic base, using ultra-violet absorption spectroscopy. In: Transactions of the Faraday Society. 1971 ; Vol. 67. pp. 3534-3539.
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Study of the dehydrochlorination of polyvinylidene chloride by alcoholic base, using ultra-violet absorption spectroscopy. / Barton, Stuart S.; Boulton, Gordon; Harrison, Brian H.; Kemp, William.

In: Transactions of the Faraday Society, Vol. 67, 1971, p. 3534-3539.

Research output: Contribution to journalArticle

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T1 - Study of the dehydrochlorination of polyvinylidene chloride by alcoholic base, using ultra-violet absorption spectroscopy

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AU - Kemp, William

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AB - Carbonization of polyvinylidene chloride by base involves abstraction of hydrogen chloride. The present work on the ultra-violet absorption spectra of partially carbonized polymer shows that this occurs predominantly by way of each molecule, in succession, losing its hydrogen chloride rapidly along the chain length. The introduction of extensive unsaturation into one molecule occurs faster than the introduction of low degrees of unsaturation into several molecules.

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