Studies on bismaleimides and related materials: 2. Synthesis and characterization of oligomeric maleimides derived from polystyrene and poly(phenylene methylene)

P. N. Preston; V. K. Shah; S. W. Simpson; I. Soutar; N. J. Stewart

Studies on bismaleimides and related materials: 2. Synthesis and characterization of oligomeric maleimides derived from polystyrene and poly(phenylene methylene)

P. N. Preston, V. K. Shah, S. W. Simpson, I. Soutar, N. J. Stewart

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Polystyrene and poly(phenylene methylene) of relatively low molar mass (2000-3000) have been converted through nitro and amino derivatives into maleimido-functionalized oligomers. The latter have been characterized spectroscopically and oligomers and cured resins derived therefrom studied by thermal gravimetric analysis. Both polystyrene and poly(phenylene methylene) show greater thermal and thermo-oxidative stability than the corresponding maleimido derivatives. This trend is also observed when comparing poly(phenylene methylene) with the crosslinked resin derived from maleimidopoly(phenylene methylene). The opposite trend is observed for polystyrene and the cured resin derived from maleimidopolystyrene. © 1994.

Original language	English
Pages (from-to)	658-662
Number of pages	5
Journal	Polymer
Volume	35
Issue number	3
Publication status	Published - Feb 1994

Keywords

bismaleimide
poly(phenylene methylene)
polystyrene

Cite this

@article{4600a6becca24a4495c1a9b34397ef8e,

title = "Studies on bismaleimides and related materials: 2. Synthesis and characterization of oligomeric maleimides derived from polystyrene and poly(phenylene methylene)",

abstract = "Polystyrene and poly(phenylene methylene) of relatively low molar mass (2000-3000) have been converted through nitro and amino derivatives into maleimido-functionalized oligomers. The latter have been characterized spectroscopically and oligomers and cured resins derived therefrom studied by thermal gravimetric analysis. Both polystyrene and poly(phenylene methylene) show greater thermal and thermo-oxidative stability than the corresponding maleimido derivatives. This trend is also observed when comparing poly(phenylene methylene) with the crosslinked resin derived from maleimidopoly(phenylene methylene). The opposite trend is observed for polystyrene and the cured resin derived from maleimidopolystyrene. {\textcopyright} 1994.",

keywords = "bismaleimide, poly(phenylene methylene), polystyrene",

author = "Preston, {P. N.} and Shah, {V. K.} and Simpson, {S. W.} and I. Soutar and Stewart, {N. J.}",

year = "1994",

month = feb,

language = "English",

volume = "35",

pages = "658--662",

journal = "Polymer",

issn = "0032-3861",

publisher = "Elsevier",

number = "3",

}

TY - JOUR

T1 - Studies on bismaleimides and related materials

T2 - 2. Synthesis and characterization of oligomeric maleimides derived from polystyrene and poly(phenylene methylene)

AU - Preston, P. N.

AU - Shah, V. K.

AU - Simpson, S. W.

AU - Soutar, I.

AU - Stewart, N. J.

PY - 1994/2

Y1 - 1994/2

N2 - Polystyrene and poly(phenylene methylene) of relatively low molar mass (2000-3000) have been converted through nitro and amino derivatives into maleimido-functionalized oligomers. The latter have been characterized spectroscopically and oligomers and cured resins derived therefrom studied by thermal gravimetric analysis. Both polystyrene and poly(phenylene methylene) show greater thermal and thermo-oxidative stability than the corresponding maleimido derivatives. This trend is also observed when comparing poly(phenylene methylene) with the crosslinked resin derived from maleimidopoly(phenylene methylene). The opposite trend is observed for polystyrene and the cured resin derived from maleimidopolystyrene. © 1994.

AB - Polystyrene and poly(phenylene methylene) of relatively low molar mass (2000-3000) have been converted through nitro and amino derivatives into maleimido-functionalized oligomers. The latter have been characterized spectroscopically and oligomers and cured resins derived therefrom studied by thermal gravimetric analysis. Both polystyrene and poly(phenylene methylene) show greater thermal and thermo-oxidative stability than the corresponding maleimido derivatives. This trend is also observed when comparing poly(phenylene methylene) with the crosslinked resin derived from maleimidopoly(phenylene methylene). The opposite trend is observed for polystyrene and the cured resin derived from maleimidopolystyrene. © 1994.

KW - bismaleimide

KW - poly(phenylene methylene)

KW - polystyrene

UR - http://www.scopus.com/inward/record.url?scp=0344805176&partnerID=8YFLogxK

M3 - Article

SN - 0032-3861

VL - 35

SP - 658

EP - 662

JO - Polymer

JF - Polymer

IS - 3

ER -

Studies on bismaleimides and related materials: 2. Synthesis and characterization of oligomeric maleimides derived from polystyrene and poly(phenylene methylene)

Abstract

Keywords

Other files and links

Fingerprint

Cite this