Structure, Reactivity, and Computational Studies of a Novel Ruthenium Hydrogen Sulfide Dihydride Complex

Sarah L. Chatwin; Richard A. Diggle; R. F R Jazzar; Stuart A. Macgregor; Mary F. Mahon; Michael K. Whittlesey

doi:10.1021/ic030241i

Structure, Reactivity, and Computational Studies of a Novel Ruthenium Hydrogen Sulfide Dihydride Complex

Sarah L. Chatwin
, Richard A. Diggle
, R. F R Jazzar
, Stuart A. Macgregor
, Mary F. Mahon
, Michael K. Whittlesey

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

Addition of 1 atm of H₂S to [Ru(IMes) ₂(CO)(EtOH)H₂] (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) affords the air-stable hydrogen sulfide dihydride complex, [Ru(IMes)₂(CO)-(H ₂S)H₂] 2. Treatment of 2 with excess H₂S leads to formation of the 16-electron bis-hydrosulfido complex, [Ru(IMes) ₂(CO)(SH)₂] 3. Preliminary studies show that 3 reacts with both H₂ and CO in solution as well as in the solid state. Both 2 and 3 have been structurally characterized.

Original language	English
Pages (from-to)	7695-7697
Number of pages	3
Journal	Inorganic Chemistry
Volume	42
Issue number	24
DOIs	https://doi.org/10.1021/ic030241i
Publication status	Published - 1 Dec 2003

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title = "Structure, Reactivity, and Computational Studies of a Novel Ruthenium Hydrogen Sulfide Dihydride Complex",

abstract = "Addition of 1 atm of H2S to [Ru(IMes) 2(CO)(EtOH)H2] (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) affords the air-stable hydrogen sulfide dihydride complex, [Ru(IMes)2(CO)-(H 2S)H2] 2. Treatment of 2 with excess H2S leads to formation of the 16-electron bis-hydrosulfido complex, [Ru(IMes) 2(CO)(SH)2] 3. Preliminary studies show that 3 reacts with both H2 and CO in solution as well as in the solid state. Both 2 and 3 have been structurally characterized.",

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year = "2003",

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doi = "10.1021/ic030241i",

language = "English",

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T1 - Structure, Reactivity, and Computational Studies of a Novel Ruthenium Hydrogen Sulfide Dihydride Complex

AU - Chatwin, Sarah L.

AU - Diggle, Richard A.

AU - Jazzar, R. F R

AU - Macgregor, Stuart A.

AU - Mahon, Mary F.

AU - Whittlesey, Michael K.

PY - 2003/12/1

Y1 - 2003/12/1

N2 - Addition of 1 atm of H2S to [Ru(IMes) 2(CO)(EtOH)H2] (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) affords the air-stable hydrogen sulfide dihydride complex, [Ru(IMes)2(CO)-(H 2S)H2] 2. Treatment of 2 with excess H2S leads to formation of the 16-electron bis-hydrosulfido complex, [Ru(IMes) 2(CO)(SH)2] 3. Preliminary studies show that 3 reacts with both H2 and CO in solution as well as in the solid state. Both 2 and 3 have been structurally characterized.

AB - Addition of 1 atm of H2S to [Ru(IMes) 2(CO)(EtOH)H2] (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) affords the air-stable hydrogen sulfide dihydride complex, [Ru(IMes)2(CO)-(H 2S)H2] 2. Treatment of 2 with excess H2S leads to formation of the 16-electron bis-hydrosulfido complex, [Ru(IMes) 2(CO)(SH)2] 3. Preliminary studies show that 3 reacts with both H2 and CO in solution as well as in the solid state. Both 2 and 3 have been structurally characterized.

UR - https://www.scopus.com/pages/publications/0344874563

U2 - 10.1021/ic030241i

DO - 10.1021/ic030241i

M3 - Article

SN - 1520-510X

VL - 42

SP - 7695

EP - 7697

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 24

ER -

Structure, Reactivity, and Computational Studies of a Novel Ruthenium Hydrogen Sulfide Dihydride Complex

Abstract

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