Structure-property relationships in polymerization of monomeric reactant type polyimide Resins. 2. New polyimides incorporating alkylenedianilines

Barry Woodfine; Ian Soutar; Peter N. Preston; Veerappa B. Jigajinni; Nevin J. Stewart; John N. Hay

Structure-property relationships in polymerization of monomeric reactant type polyimide Resins. 2. New polyimides incorporating alkylenedianilines

Barry Woodfine, Ian Soutar, Peter N. Preston, Veerappa B. Jigajinni, Nevin J. Stewart, John N. Hay

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

New polyimide thermoset resins have been synthesized incorporating alkylenedianilines as the diamine components. The variations in intrinsic chain mobility resultant upon differences in the alkylene chain lengths produced cured resins which exhibited a wide range of T_g values (290-386°C). The structural variants of diamine within the resin formulations also effected lowering of the apparent onset temperatures for cross-linking, during cure, as the alkylene "spacer" units were extended. All resins exhibited good thermal and thermooxidative stabilities, with temperatures for 10% weight loss in the region of 450-500°C. © 1993 American Chemical Society.

Original language	English
Pages (from-to)	6330-6334
Number of pages	5
Journal	Macromolecules
Volume	26
Issue number	24
Publication status	Published - 1993

Cite this

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title = "Structure-property relationships in polymerization of monomeric reactant type polyimide Resins. 2. New polyimides incorporating alkylenedianilines",

abstract = "New polyimide thermoset resins have been synthesized incorporating alkylenedianilines as the diamine components. The variations in intrinsic chain mobility resultant upon differences in the alkylene chain lengths produced cured resins which exhibited a wide range of Tg values (290-386°C). The structural variants of diamine within the resin formulations also effected lowering of the apparent onset temperatures for cross-linking, during cure, as the alkylene {"}spacer{"} units were extended. All resins exhibited good thermal and thermooxidative stabilities, with temperatures for 10% weight loss in the region of 450-500°C. {\textcopyright} 1993 American Chemical Society.",

author = "Barry Woodfine and Ian Soutar and Preston, {Peter N.} and Jigajinni, {Veerappa B.} and Stewart, {Nevin J.} and Hay, {John N.}",

year = "1993",

language = "English",

volume = "26",

pages = "6330--6334",

journal = "Macromolecules",

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publisher = "American Chemical Society",

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T1 - Structure-property relationships in polymerization of monomeric reactant type polyimide Resins. 2. New polyimides incorporating alkylenedianilines

AU - Woodfine, Barry

AU - Soutar, Ian

AU - Preston, Peter N.

AU - Jigajinni, Veerappa B.

AU - Stewart, Nevin J.

AU - Hay, John N.

PY - 1993

Y1 - 1993

N2 - New polyimide thermoset resins have been synthesized incorporating alkylenedianilines as the diamine components. The variations in intrinsic chain mobility resultant upon differences in the alkylene chain lengths produced cured resins which exhibited a wide range of Tg values (290-386°C). The structural variants of diamine within the resin formulations also effected lowering of the apparent onset temperatures for cross-linking, during cure, as the alkylene "spacer" units were extended. All resins exhibited good thermal and thermooxidative stabilities, with temperatures for 10% weight loss in the region of 450-500°C. © 1993 American Chemical Society.

AB - New polyimide thermoset resins have been synthesized incorporating alkylenedianilines as the diamine components. The variations in intrinsic chain mobility resultant upon differences in the alkylene chain lengths produced cured resins which exhibited a wide range of Tg values (290-386°C). The structural variants of diamine within the resin formulations also effected lowering of the apparent onset temperatures for cross-linking, during cure, as the alkylene "spacer" units were extended. All resins exhibited good thermal and thermooxidative stabilities, with temperatures for 10% weight loss in the region of 450-500°C. © 1993 American Chemical Society.

UR - http://www.scopus.com/inward/record.url?scp=0027698286&partnerID=8YFLogxK

M3 - Article

SN - 0024-9297

VL - 26

SP - 6330

EP - 6334

JO - Macromolecules

JF - Macromolecules

IS - 24

ER -

Structure-property relationships in polymerization of monomeric reactant type polyimide Resins. 2. New polyimides incorporating alkylenedianilines

Abstract

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