Structure of the trans-dimer of 2-methyl-2-nitrosopropane

Brian G. Gowenlock; Kevin J. McCullough; Ross B. Manson

Structure of the trans-dimer of 2-methyl-2-nitrosopropane

Brian G. Gowenlock, Kevin J. McCullough, Ross B. Manson

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

The crystal structure of the trans-dimer of 2-methyl-2-nitrosopropane has been established by X-ray diffraction studies. The crystals are monoclinic, space group P2₁/n, with Z = 2 and unit-cell constants a = 5.929 0(18), b = 10.112(3), c = 8.751 (4) Å, and ß = 90.80(3)°. Although the NN- and ON-bond distances are normal for nitroso compounds, the CN-distance was significantly longer than expected.

Original language	English
Pages (from-to)	701-703
Number of pages	3
Journal	Journal of the Chemical Society, Perkin Transactions 2
Issue number	5
Publication status	Published - 1988

Cite this

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title = "Structure of the trans-dimer of 2-methyl-2-nitrosopropane",

abstract = "The crystal structure of the trans-dimer of 2-methyl-2-nitrosopropane has been established by X-ray diffraction studies. The crystals are monoclinic, space group P21/n, with Z = 2 and unit-cell constants a = 5.929 0(18), b = 10.112(3), c = 8.751 (4) {\AA}, and {\ss} = 90.80(3)°. Although the NN- and ON-bond distances are normal for nitroso compounds, the CN-distance was significantly longer than expected.",

author = "Gowenlock, \{Brian G.\} and McCullough, \{Kevin J.\} and Manson, \{Ross B.\}",

year = "1988",

language = "English",

pages = "701--703",

journal = "Journal of the Chemical Society, Perkin Transactions 2",

issn = "1472-779X",

publisher = "Royal Society of Chemistry",

number = "5",

}

TY - JOUR

T1 - Structure of the trans-dimer of 2-methyl-2-nitrosopropane

AU - Gowenlock, Brian G.

AU - McCullough, Kevin J.

AU - Manson, Ross B.

PY - 1988

Y1 - 1988

N2 - The crystal structure of the trans-dimer of 2-methyl-2-nitrosopropane has been established by X-ray diffraction studies. The crystals are monoclinic, space group P21/n, with Z = 2 and unit-cell constants a = 5.929 0(18), b = 10.112(3), c = 8.751 (4) Å, and ß = 90.80(3)°. Although the NN- and ON-bond distances are normal for nitroso compounds, the CN-distance was significantly longer than expected.

AB - The crystal structure of the trans-dimer of 2-methyl-2-nitrosopropane has been established by X-ray diffraction studies. The crystals are monoclinic, space group P21/n, with Z = 2 and unit-cell constants a = 5.929 0(18), b = 10.112(3), c = 8.751 (4) Å, and ß = 90.80(3)°. Although the NN- and ON-bond distances are normal for nitroso compounds, the CN-distance was significantly longer than expected.

UR - https://www.scopus.com/pages/publications/37049077274

M3 - Article

SN - 1472-779X

SP - 701

EP - 703

JO - Journal of the Chemical Society, Perkin Transactions 2

JF - Journal of the Chemical Society, Perkin Transactions 2

IS - 5

ER -

Structure of the trans-dimer of 2-methyl-2-nitrosopropane

Abstract

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