Structure determination of substituted rutiles by time-of-flight neutron diffraction

I. Abrahams; P. G. Bruce; W. I F David; A. R. West

Structure determination of substituted rutiles by time-of-flight neutron diffraction

I. Abrahams, P. G. Bruce, W. I F David, A. R. West

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

High-resolution time-of-flight neutron diffraction has been used to determine the structures of three cation-substituted rutile materials, viz., Zn_0.15Nb_0.3Ti_0.55O₂, Al_0.2Nb_0.2Ti_0.6O₂, and Li_0.15Nb_0.45Ti_0.4O₂. The three materials maintain the basic rutile framework with cations located in the titanium site of space group P4₂/mnm. Only Li_0.15Nb_0.45Ti_0.4O₂ showed any occupation of the channels that exist in these structures, with Li at 1/2,0,0 and 1/2,0,1/4 as well as in the framework site. © 1989 American Chemical Society.

Original language	English
Pages (from-to)	237-240
Number of pages	4
Journal	Chemistry of Materials
Volume	1
Issue number	2
Publication status	Published - 1989

Cite this

@article{ddbb870d83ff4f9d8ac2f3dc40bf7dac,

title = "Structure determination of substituted rutiles by time-of-flight neutron diffraction",

abstract = "High-resolution time-of-flight neutron diffraction has been used to determine the structures of three cation-substituted rutile materials, viz., Zn0.15Nb0.3Ti0.55O2, Al0.2Nb0.2Ti0.6O2, and Li0.15Nb0.45Ti0.4O2. The three materials maintain the basic rutile framework with cations located in the titanium site of space group P42/mnm. Only Li0.15Nb0.45Ti0.4O2 showed any occupation of the channels that exist in these structures, with Li at 1/2,0,0 and 1/2,0,1/4 as well as in the framework site. {\textcopyright} 1989 American Chemical Society.",

author = "I. Abrahams and Bruce, {P. G.} and David, {W. I F} and West, {A. R.}",

year = "1989",

language = "English",

volume = "1",

pages = "237--240",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "American Chemical Society",

number = "2",

}

TY - JOUR

T1 - Structure determination of substituted rutiles by time-of-flight neutron diffraction

AU - Abrahams, I.

AU - Bruce, P. G.

AU - David, W. I F

AU - West, A. R.

PY - 1989

Y1 - 1989

N2 - High-resolution time-of-flight neutron diffraction has been used to determine the structures of three cation-substituted rutile materials, viz., Zn0.15Nb0.3Ti0.55O2, Al0.2Nb0.2Ti0.6O2, and Li0.15Nb0.45Ti0.4O2. The three materials maintain the basic rutile framework with cations located in the titanium site of space group P42/mnm. Only Li0.15Nb0.45Ti0.4O2 showed any occupation of the channels that exist in these structures, with Li at 1/2,0,0 and 1/2,0,1/4 as well as in the framework site. © 1989 American Chemical Society.

AB - High-resolution time-of-flight neutron diffraction has been used to determine the structures of three cation-substituted rutile materials, viz., Zn0.15Nb0.3Ti0.55O2, Al0.2Nb0.2Ti0.6O2, and Li0.15Nb0.45Ti0.4O2. The three materials maintain the basic rutile framework with cations located in the titanium site of space group P42/mnm. Only Li0.15Nb0.45Ti0.4O2 showed any occupation of the channels that exist in these structures, with Li at 1/2,0,0 and 1/2,0,1/4 as well as in the framework site. © 1989 American Chemical Society.

UR - http://www.scopus.com/inward/record.url?scp=33845183491&partnerID=8YFLogxK

M3 - Article

SN - 0897-4756

VL - 1

SP - 237

EP - 240

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 2

ER -

Structure determination of substituted rutiles by time-of-flight neutron diffraction

Abstract

Other files and links

Fingerprint

Cite this