Structure and phase behavior of a 2: 1 complex between arene- and fluoroarene-based conjugated rigid rods

Stephen W. Watt; Chaoyang Dai; Andrew J. Scott; Jacquelyn M. Burke; Rhodri Ll Thomas; Jonathan C. Collings; Christopher Viney; William Clegg; Todd B. Marder

doi:10.1002/anie.200453828

Structure and phase behavior of a 2: 1 complex between arene- and fluoroarene-based conjugated rigid rods

Stephen W. Watt, Chaoyang Dai, Andrew J. Scott, Jacquelyn M. Burke, Rhodri Ll Thomas, Jonathan C. Collings, Christopher Viney, William Clegg, Todd B. Marder

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

130 Citations (Scopus)

Abstract

The ps have it: An unusual 2:1 areneperfluoroarene p complex is formed between 1,4-bis(phenylethynyl)benzene and its perfluorinated analogue, and this is the first example of a non-1:1 complex of this type. The interstack geometry (see picture; red H, green F) is also unusual, as is the complex mesomorphism of this system.

Original language	English
Pages (from-to)	3061-3063
Number of pages	3
Journal	Angewandte Chemie International Edition
Volume	43
Issue number	23
DOIs	https://doi.org/10.1002/anie.200453828
Publication status	Published - 7 Jun 2004

Keywords

Crystal engineering
Fluorine
Liquid crystals
Pi interactions
Supramolecular chemistry

Access to Document

10.1002/anie.200453828

Cite this

@article{8c98cde7b1994f0a8518179cab21e544,

title = "Structure and phase behavior of a 2: 1 complex between arene- and fluoroarene-based conjugated rigid rods",

abstract = "The ps have it: An unusual 2:1 areneperfluoroarene p complex is formed between 1,4-bis(phenylethynyl)benzene and its perfluorinated analogue, and this is the first example of a non-1:1 complex of this type. The interstack geometry (see picture; red H, green F) is also unusual, as is the complex mesomorphism of this system.",

keywords = "Crystal engineering, Fluorine, Liquid crystals, Pi interactions, Supramolecular chemistry",

author = "Watt, {Stephen W.} and Chaoyang Dai and Scott, {Andrew J.} and Burke, {Jacquelyn M.} and Thomas, {Rhodri Ll} and Collings, {Jonathan C.} and Christopher Viney and William Clegg and Marder, {Todd B.}",

year = "2004",

month = jun,

day = "7",

doi = "10.1002/anie.200453828",

language = "English",

volume = "43",

pages = "3061--3063",

journal = "Angewandte Chemie International Edition",

issn = "1521-3773",

publisher = "John Wiley and Sons Ltd",

number = "23",

}

TY - JOUR

T1 - Structure and phase behavior of a 2

T2 - 1 complex between arene- and fluoroarene-based conjugated rigid rods

AU - Watt, Stephen W.

AU - Dai, Chaoyang

AU - Scott, Andrew J.

AU - Burke, Jacquelyn M.

AU - Thomas, Rhodri Ll

AU - Collings, Jonathan C.

AU - Viney, Christopher

AU - Clegg, William

AU - Marder, Todd B.

PY - 2004/6/7

Y1 - 2004/6/7

N2 - The ps have it: An unusual 2:1 areneperfluoroarene p complex is formed between 1,4-bis(phenylethynyl)benzene and its perfluorinated analogue, and this is the first example of a non-1:1 complex of this type. The interstack geometry (see picture; red H, green F) is also unusual, as is the complex mesomorphism of this system.

AB - The ps have it: An unusual 2:1 areneperfluoroarene p complex is formed between 1,4-bis(phenylethynyl)benzene and its perfluorinated analogue, and this is the first example of a non-1:1 complex of this type. The interstack geometry (see picture; red H, green F) is also unusual, as is the complex mesomorphism of this system.

KW - Crystal engineering

KW - Fluorine

KW - Liquid crystals

KW - Pi interactions

KW - Supramolecular chemistry

UR - http://www.scopus.com/inward/record.url?scp=4544376455&partnerID=8YFLogxK

U2 - 10.1002/anie.200453828

DO - 10.1002/anie.200453828

M3 - Article

SN - 1521-3773

VL - 43

SP - 3061

EP - 3063

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 23

ER -

Structure and phase behavior of a 2: 1 complex between arene- and fluoroarene-based conjugated rigid rods

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this