Structural diversity of methyl-substituted inclusion complexes of calix[5]arene

Thomas E Clark, Mohamed Makha, Alexandre N Sobolev, Scott J Dalgarno, Jerry L Atwood, Colin L Raston

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

The three isomers of xylene form inclusion complexes with p-H-calix[5]arene with different spatial interplay of the cavitands, which is relevant to using crystallization as a means of separating mixtures of o-, m-, and p-xylenes. Competition experiments involving mixtures of o-/m-xylene, o-/p-xylene, and m-/p-xylene and a mixture of all three isomers showed some selectivity in the inclusion of the xylenes with p-H-calix[5]arene according to the inequality m- > o- > p-xylene. Also reported are the toluene and mesitylene solvates, which are isostructural with the o-xylene and m-xylene inclusion complexes, respectively.
Original languageEnglish
Pages (from-to)2059-2065
Number of pages7
JournalCrystal Growth and Design
Volume7
Issue number10
DOIs
Publication statusPublished - Oct 2007

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