Structural and theoretical studies of intermolecular dihydrogen bonding in [(C6F5)2(C6Cl5)B]–H⋯H–[TMP]

Hasna Zaher; Andrew E. Ashley; Mark Irwin; Amber L. Thompson; Matthias J. Gutmann; Tobias Kraemer; Dermot O'Hare

doi:10.1039/c3cc45889j

Structural and theoretical studies of intermolecular dihydrogen bonding in [(C6F5)2(C6Cl5)B]–H⋯H–[TMP]

Hasna Zaher, Andrew E. Ashley^*, Mark Irwin, Amber L. Thompson, Matthias J. Gutmann, Tobias Kraemer, Dermot O'Hare

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

The product of the intermolecular 'frustrated Lewis pair' (FLP) B(C6F5)(2)(C6Cl5)/2,2,6,6-tetramethylpiperidine and H-2 has been studied by single-crystal neutron diffraction. This is the first structurally characterised example of a geometrically unconstrained dihydrogen (H center dot center dot center dot H) bond within a hydrogenated FLP system.

Original language	English
Pages (from-to)	9755-9757
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	84
DOIs	https://doi.org/10.1039/c3cc45889j
Publication status	Published - Oct 2013

Keywords

FRUSTRATED LEWIS PAIRS
FREE HYDROGEN ACTIVATION
H-2 ACTIVATION
REACTIVITY
PHOSPHINES
REDUCTION
MECHANISM
BORANES
ACIDITY
CO2

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title = "Structural and theoretical studies of intermolecular dihydrogen bonding in [(C6F5)2(C6Cl5)B]–H⋯H–[TMP]",

abstract = "The product of the intermolecular 'frustrated Lewis pair' (FLP) B(C6F5)(2)(C6Cl5)/2,2,6,6-tetramethylpiperidine and H-2 has been studied by single-crystal neutron diffraction. This is the first structurally characterised example of a geometrically unconstrained dihydrogen (H center dot center dot center dot H) bond within a hydrogenated FLP system.",

keywords = "FRUSTRATED LEWIS PAIRS, FREE HYDROGEN ACTIVATION, H-2 ACTIVATION, REACTIVITY, PHOSPHINES, REDUCTION, MECHANISM, BORANES, ACIDITY, CO2",

author = "Hasna Zaher and Ashley, {Andrew E.} and Mark Irwin and Thompson, {Amber L.} and Gutmann, {Matthias J.} and Tobias Kraemer and Dermot O'Hare",

year = "2013",

month = oct,

doi = "10.1039/c3cc45889j",

language = "English",

volume = "49",

pages = "9755--9757",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "84",

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TY - JOUR

T1 - Structural and theoretical studies of intermolecular dihydrogen bonding in [(C6F5)2(C6Cl5)B]–H⋯H–[TMP]

AU - Zaher, Hasna

AU - Ashley, Andrew E.

AU - Irwin, Mark

AU - Thompson, Amber L.

AU - Gutmann, Matthias J.

AU - Kraemer, Tobias

AU - O'Hare, Dermot

PY - 2013/10

Y1 - 2013/10

N2 - The product of the intermolecular 'frustrated Lewis pair' (FLP) B(C6F5)(2)(C6Cl5)/2,2,6,6-tetramethylpiperidine and H-2 has been studied by single-crystal neutron diffraction. This is the first structurally characterised example of a geometrically unconstrained dihydrogen (H center dot center dot center dot H) bond within a hydrogenated FLP system.

AB - The product of the intermolecular 'frustrated Lewis pair' (FLP) B(C6F5)(2)(C6Cl5)/2,2,6,6-tetramethylpiperidine and H-2 has been studied by single-crystal neutron diffraction. This is the first structurally characterised example of a geometrically unconstrained dihydrogen (H center dot center dot center dot H) bond within a hydrogenated FLP system.

KW - FRUSTRATED LEWIS PAIRS

KW - FREE HYDROGEN ACTIVATION

KW - H-2 ACTIVATION

KW - REACTIVITY

KW - PHOSPHINES

KW - REDUCTION

KW - MECHANISM

KW - BORANES

KW - ACIDITY

KW - CO2

U2 - 10.1039/c3cc45889j

DO - 10.1039/c3cc45889j

M3 - Article

C2 - 24037274

SN - 1359-7345

VL - 49

SP - 9755

EP - 9757

JO - Chemical Communications

JF - Chemical Communications

IS - 84

ER -

Structural and theoretical studies of intermolecular dihydrogen bonding in [(C6F5)2(C6Cl5)B]–H⋯H–[TMP]

Abstract

Keywords

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