TY - JOUR
T1 - Structural and dynamical characterization of melt PEO-salt mixtures
AU - Triolo, A.
AU - Lo Celso, F.
AU - Arrighi, V.
AU - Strunz, P.
AU - Lechner, R. E.
AU - Mastragostino, M.
AU - Passerini, S.
AU - Annis, B. K.
AU - Triolo, R.
PY - 2002/2/1
Y1 - 2002/2/1
N2 - Salt doped poly ethylene oxide (PEO) mixtures were investigated by means of both small angle neutron scattering and QENS techniques aiming to characterize morphological and dynamical features in the melt state. These experimental evidences provide support to the proposed heterogeneous scenario for polymer electrolytes. In particular, the existence of PEO-cation complexes is proposed to play a major role in intramolecular cooperation and intermolecular transient crosslinks, which affects the mixture properties. © 2002 Elsevier Science B.V. All rights reserved.
AB - Salt doped poly ethylene oxide (PEO) mixtures were investigated by means of both small angle neutron scattering and QENS techniques aiming to characterize morphological and dynamical features in the melt state. These experimental evidences provide support to the proposed heterogeneous scenario for polymer electrolytes. In particular, the existence of PEO-cation complexes is proposed to play a major role in intramolecular cooperation and intermolecular transient crosslinks, which affects the mixture properties. © 2002 Elsevier Science B.V. All rights reserved.
UR - http://www.scopus.com/inward/record.url?scp=0036468114&partnerID=8YFLogxK
U2 - 10.1016/S0378-4371(01)00536-2
DO - 10.1016/S0378-4371(01)00536-2
M3 - Article
VL - 304
SP - 308
EP - 313
JO - Physica A: Statistical Mechanics and its Applications
JF - Physica A: Statistical Mechanics and its Applications
SN - 0378-4371
IS - 1-2
T2 - Scattering Sudies of Mesoscopic Scale Structure and Dynamics
Y2 - 22 November 2001 through 25 November 2001
ER -