Strategies for stable water splitting: Via protected photoelectrodes

Dowon Bae, Brian Seger, Peter C. K. Vesborg, Ole Hansen, Ib Chorkendorff*

*Corresponding author for this work

Research output: Contribution to journalReview articlepeer-review

433 Citations (Scopus)


Photoelectrochemical (PEC) solar-fuel conversion is a promising approach to provide clean and storable fuel (e.g., hydrogen and methanol) directly from sunlight, water and CO2. However, major challenges still have to be overcome before commercialization can be achieved. One of the largest barriers to overcome is to achieve a stable PEC reaction in either strongly basic or acidic electrolytes without degradation of the semiconductor photoelectrodes. In this work, we discuss fundamental aspects of protection strategies for achieving stable solid/liquid interfaces. We then analyse the charge transfer mechanism through the protection layers for both photoanodes and photocathodes. In addition, we review protection layer approaches and their stabilities for a wide variety of experimental photoelectrodes for water reduction. Finally, we discuss key aspects which should be addressed in continued work on realizing stable and practical PEC solar water splitting systems.

Original languageEnglish
Pages (from-to)1933-1954
Number of pages22
JournalChemical Society Reviews
Issue number7
Early online date1 Mar 2017
Publication statusPublished - 7 Apr 2017

ASJC Scopus subject areas

  • General Chemistry


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