Steric Control of Sorting Regimes in Self-Assembled Cages

Samuel Edward Walker, Stephanie A. Boer, Thomas Malcomson, Martin J. Paterson, Kellie L. Tuck, David Roger Turner

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)
14 Downloads (Pure)


Control of self-sorting regimes is achieved through adjustment of steric interactions in self-assembled coordination cages. The self-assembly regime of dynamic mixtures of heteroleptic cages is followed by HPLC to show that statistical or biased distributions can be selectively obtained, including isolation of a single heteroleptic species.
Original languageEnglish
Pages (from-to)12456-12459
Number of pages4
JournalChemical Communications
Issue number93
Early online date29 Oct 2021
Publication statusPublished - 4 Dec 2021

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry


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