Steric Control of Sorting Regimes in Self-Assembled Cages

Samuel Edward Walker; Stephanie A. Boer; Thomas Malcomson; Martin J. Paterson; Kellie L. Tuck; David Roger Turner

doi:10.1039/D1CC05610G

Steric Control of Sorting Regimes in Self-Assembled Cages

Samuel Edward Walker, Stephanie A. Boer, Thomas Malcomson, Martin J. Paterson, Kellie L. Tuck, David Roger Turner

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21 Citations (Scopus)

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Abstract

Control of self-sorting regimes is achieved through adjustment of steric interactions in self-assembled coordination cages. The self-assembly regime of dynamic mixtures of heteroleptic cages is followed by HPLC to show that statistical or biased distributions can be selectively obtained, including isolation of a single heteroleptic species.

Original language	English
Pages (from-to)	12456-12459
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	93
Early online date	29 Oct 2021
DOIs	https://doi.org/10.1039/D1CC05610G
Publication status	Published - 4 Dec 2021

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Steric Control of Sorting Regimes in Self-Assembled Cages",

abstract = "Control of self-sorting regimes is achieved through adjustment of steric interactions in self-assembled coordination cages. The self-assembly regime of dynamic mixtures of heteroleptic cages is followed by HPLC to show that statistical or biased distributions can be selectively obtained, including isolation of a single heteroleptic species.",

author = "Walker, {Samuel Edward} and Boer, {Stephanie A.} and Thomas Malcomson and Paterson, {Martin J.} and Tuck, {Kellie L.} and Turner, {David Roger}",

note = "Funding Information: DRT acknowledges the ARC (DP210100347). SEW, SAB thanks the Australian Government for RTP scholarships. Part of this work was conducted using the MX2 beamline at the Australian Synchrotron, part of ANSTO, and made use of the ACRF detector. MJP thanks EPSRC for funding through grants EP/P001459/1, EP/T021675/1 and EP/V006746/1. TM thanks the High End Computing Facility at Lancaster University. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

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AU - Walker, Samuel Edward

AU - Boer, Stephanie A.

AU - Malcomson, Thomas

AU - Paterson, Martin J.

AU - Tuck, Kellie L.

AU - Turner, David Roger

N1 - Funding Information: DRT acknowledges the ARC (DP210100347). SEW, SAB thanks the Australian Government for RTP scholarships. Part of this work was conducted using the MX2 beamline at the Australian Synchrotron, part of ANSTO, and made use of the ACRF detector. MJP thanks EPSRC for funding through grants EP/P001459/1, EP/T021675/1 and EP/V006746/1. TM thanks the High End Computing Facility at Lancaster University. Publisher Copyright: © The Royal Society of Chemistry.

PY - 2021/12/4

Y1 - 2021/12/4

N2 - Control of self-sorting regimes is achieved through adjustment of steric interactions in self-assembled coordination cages. The self-assembly regime of dynamic mixtures of heteroleptic cages is followed by HPLC to show that statistical or biased distributions can be selectively obtained, including isolation of a single heteroleptic species.

AB - Control of self-sorting regimes is achieved through adjustment of steric interactions in self-assembled coordination cages. The self-assembly regime of dynamic mixtures of heteroleptic cages is followed by HPLC to show that statistical or biased distributions can be selectively obtained, including isolation of a single heteroleptic species.

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U2 - 10.1039/D1CC05610G

DO - 10.1039/D1CC05610G

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EP - 12459

JO - Chemical Communications

JF - Chemical Communications

IS - 93

ER -

Steric Control of Sorting Regimes in Self-Assembled Cages

Abstract

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