Stellated cuboctahedron of FeIII

Lucinda R. B. Wilson; Angelos B. Canaj; Daniel J. Cutler; Laura J. McCormick McPherson; Simon J. Coles; Hiroyuki Nojiri; Marco Evangelisti; Jürgen Schnack; Scott J. Dalgarno; Euan K. Brechin

doi:10.1002/ange.202405666

Stellated cuboctahedron of FeIII

Lucinda R. B. Wilson, Angelos B. Canaj, Daniel J. Cutler, Laura J. McCormick McPherson, Simon J. Coles, Hiroyuki Nojiri^*, Marco Evangelisti^*, Jürgen Schnack^*, Scott J. Dalgarno^*, Euan K. Brechin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

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Abstract

The solvothermal reaction of FeCl2 ⋅ 4H2O and H4TBC[4] in a basic dmf/EtOH solution affords an [FeIII18] Keplerate conforming to a stellated cuboctahedron. Magnetic and heat capacity measurements reveal spin frustration effects arising from the high symmetry. A crossover between inverse and direct magnetocaloric effects is observed at ~10 K for applied-field changes lower than 3 T.

Original language	English
Article number	e202405666
Journal	Angewandte Chemie
Volume	136
Issue number	37
Early online date	1 Aug 2024
DOIs	https://doi.org/10.1002/ange.202405666
Publication status	Published - 1 Sept 2024

Keywords

FeIII
calix[4]arene
magnetic measurements
spin frustration
stellated cuboctahedron

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Cite this

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title = "Stellated cuboctahedron of FeIII",

abstract = "The solvothermal reaction of FeCl2 ⋅ 4H2O and H4TBC[4] in a basic dmf/EtOH solution affords an [FeIII18] Keplerate conforming to a stellated cuboctahedron. Magnetic and heat capacity measurements reveal spin frustration effects arising from the high symmetry. A crossover between inverse and direct magnetocaloric effects is observed at \textasciitilde{}10 K for applied-field changes lower than 3 T.",

keywords = "FeIII, calix[4]arene, magnetic measurements, spin frustration, stellated cuboctahedron",

author = "Wilson, \{Lucinda R. B.\} and Canaj, \{Angelos B.\} and Cutler, \{Daniel J.\} and \{McCormick McPherson\}, \{Laura J.\} and Coles, \{Simon J.\} and Hiroyuki Nojiri and Marco Evangelisti and J{\"u}rgen Schnack and Dalgarno, \{Scott J.\} and Brechin, \{Euan K.\}",

note = "Publisher Copyright: {\textcopyright} 2024 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.",

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month = sep,

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doi = "10.1002/ange.202405666",

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T1 - Stellated cuboctahedron of FeIII

AU - Wilson, Lucinda R. B.

AU - Canaj, Angelos B.

AU - Cutler, Daniel J.

AU - McCormick McPherson, Laura J.

AU - Coles, Simon J.

AU - Nojiri, Hiroyuki

AU - Evangelisti, Marco

AU - Schnack, Jürgen

AU - Dalgarno, Scott J.

AU - Brechin, Euan K.

PY - 2024/9/1

Y1 - 2024/9/1

N2 - The solvothermal reaction of FeCl2 ⋅ 4H2O and H4TBC[4] in a basic dmf/EtOH solution affords an [FeIII18] Keplerate conforming to a stellated cuboctahedron. Magnetic and heat capacity measurements reveal spin frustration effects arising from the high symmetry. A crossover between inverse and direct magnetocaloric effects is observed at ~10 K for applied-field changes lower than 3 T.

AB - The solvothermal reaction of FeCl2 ⋅ 4H2O and H4TBC[4] in a basic dmf/EtOH solution affords an [FeIII18] Keplerate conforming to a stellated cuboctahedron. Magnetic and heat capacity measurements reveal spin frustration effects arising from the high symmetry. A crossover between inverse and direct magnetocaloric effects is observed at ~10 K for applied-field changes lower than 3 T.

KW - FeIII

KW - calix[4]arene

KW - magnetic measurements

KW - spin frustration

KW - stellated cuboctahedron

UR - https://www.scopus.com/pages/publications/85200141159

U2 - 10.1002/ange.202405666

DO - 10.1002/ange.202405666

M3 - Article

C2 - 38884268

SN - 0044-8249

VL - 136

JO - Angewandte Chemie

JF - Angewandte Chemie

IS - 37

M1 - e202405666

ER -

Stellated cuboctahedron of FeIII

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