Stable, easily sintered BaCe0.5Zr0.3y 0.16Zn0.04O3-δ electrolyte-based protonic ceramic membrane fuel cells with Ba0.5Sr0.5Zn 0.2Fe0.8O3-δ perovskite cathode

Bin Lin; Mingjun Hu; Jianjun Ma; Yinzhu Jiang; Shanwen Tao; Guangyao Meng

doi:10.1016/j.jpowsour.2008.05.075

Stable, easily sintered BaCe_0.5Zr_0.3y _0.16Zn_0.04O_3-δ electrolyte-based protonic ceramic membrane fuel cells with Ba_0.5Sr_0.5Zn _0.2Fe_0.8O_3-δ perovskite cathode

Bin Lin
, Mingjun Hu
, Jianjun Ma
, Yinzhu Jiang
, Shanwen Tao
, Guangyao Meng

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

54 Citations (Scopus)

Abstract

Astable, easily sintered perovskite oxide BaCe_0.5Zr _0.3Ya_0.16Zn_0.04O_3-d (BCZYZn) as an electrolyte for protonic ceramic membrane fuel cells (PCMFCs) with Ba _0.5Sr_0.5Zn_0.2Fe_0.8O _3-d (BSZF) perovskite cathode was investigated. The BCZYZn perovskite electrolyte synthesized by a modified Pechini method exhibited higher sinterability and reached 97.4% relative density at 1200°C for 5 h in air, which is about 200°C lower than that without Zn dopant. By fabricating thin membrane BCZYZn electrolyte (about 30 µm in thickness) on NiO-BCZYZn anode support, PCMFCs were assembled and tested by selecting stable BSZF perovskite cathode. An open-circuit potential of 1.00 V, a maximum power density of 236 mWcm^-2, and a low polarization resistance of the electrodes of 0.17 O cm² were achieved at 700°C. This investigation indicated that proton conducting electrolyte BCZYZn with BSZF perovskite cathode is a promising material system for the next generation solid oxide fuel cells. © 2008 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	479-484
Number of pages	6
Journal	Journal of Power Sources
Volume	183
Issue number	2
DOIs	https://doi.org/10.1016/j.jpowsour.2008.05.075
Publication status	Published - 1 Sept 2008

Keywords

Ba 0.5 Sr 0.5 Zn 0.2 Fe 0.8 O 3-δ
BaCe 0.5 Zr 0.3 Y 0.16 Zn 0.04 O 3-δ
Pechini method
Solid oxide fuel cells
Zn dopant

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10.1016/j.jpowsour.2008.05.075

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title = "Stable, easily sintered BaCe0.5Zr0.3y 0.16Zn0.04O3-δ electrolyte-based protonic ceramic membrane fuel cells with Ba0.5Sr0.5Zn 0.2Fe0.8O3-δ perovskite cathode",

abstract = "Astable, easily sintered perovskite oxide BaCe0.5Zr 0.3Ya0.16Zn0.04O3-d (BCZYZn) as an electrolyte for protonic ceramic membrane fuel cells (PCMFCs) with Ba 0.5Sr0.5Zn0.2Fe0.8O 3-d (BSZF) perovskite cathode was investigated. The BCZYZn perovskite electrolyte synthesized by a modified Pechini method exhibited higher sinterability and reached 97.4\% relative density at 1200°C for 5 h in air, which is about 200°C lower than that without Zn dopant. By fabricating thin membrane BCZYZn electrolyte (about 30 µm in thickness) on NiO-BCZYZn anode support, PCMFCs were assembled and tested by selecting stable BSZF perovskite cathode. An open-circuit potential of 1.00 V, a maximum power density of 236 mWcm-2, and a low polarization resistance of the electrodes of 0.17 O cm2 were achieved at 700°C. This investigation indicated that proton conducting electrolyte BCZYZn with BSZF perovskite cathode is a promising material system for the next generation solid oxide fuel cells. {\textcopyright} 2008 Elsevier B.V. All rights reserved.",

keywords = "Ba 0.5 Sr 0.5 Zn 0.2 Fe 0.8 O 3-δ, BaCe 0.5 Zr 0.3 Y 0.16 Zn 0.04 O 3-δ, Pechini method, Solid oxide fuel cells, Zn dopant",

author = "Bin Lin and Mingjun Hu and Jianjun Ma and Yinzhu Jiang and Shanwen Tao and Guangyao Meng",

year = "2008",

month = sep,

day = "1",

doi = "10.1016/j.jpowsour.2008.05.075",

language = "English",

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pages = "479--484",

journal = "Journal of Power Sources",

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TY - JOUR

T1 - Stable, easily sintered BaCe0.5Zr0.3y 0.16Zn0.04O3-δ electrolyte-based protonic ceramic membrane fuel cells with Ba0.5Sr0.5Zn 0.2Fe0.8O3-δ perovskite cathode

AU - Lin, Bin

AU - Hu, Mingjun

AU - Ma, Jianjun

AU - Jiang, Yinzhu

AU - Tao, Shanwen

AU - Meng, Guangyao

PY - 2008/9/1

Y1 - 2008/9/1

N2 - Astable, easily sintered perovskite oxide BaCe0.5Zr 0.3Ya0.16Zn0.04O3-d (BCZYZn) as an electrolyte for protonic ceramic membrane fuel cells (PCMFCs) with Ba 0.5Sr0.5Zn0.2Fe0.8O 3-d (BSZF) perovskite cathode was investigated. The BCZYZn perovskite electrolyte synthesized by a modified Pechini method exhibited higher sinterability and reached 97.4% relative density at 1200°C for 5 h in air, which is about 200°C lower than that without Zn dopant. By fabricating thin membrane BCZYZn electrolyte (about 30 µm in thickness) on NiO-BCZYZn anode support, PCMFCs were assembled and tested by selecting stable BSZF perovskite cathode. An open-circuit potential of 1.00 V, a maximum power density of 236 mWcm-2, and a low polarization resistance of the electrodes of 0.17 O cm2 were achieved at 700°C. This investigation indicated that proton conducting electrolyte BCZYZn with BSZF perovskite cathode is a promising material system for the next generation solid oxide fuel cells. © 2008 Elsevier B.V. All rights reserved.

AB - Astable, easily sintered perovskite oxide BaCe0.5Zr 0.3Ya0.16Zn0.04O3-d (BCZYZn) as an electrolyte for protonic ceramic membrane fuel cells (PCMFCs) with Ba 0.5Sr0.5Zn0.2Fe0.8O 3-d (BSZF) perovskite cathode was investigated. The BCZYZn perovskite electrolyte synthesized by a modified Pechini method exhibited higher sinterability and reached 97.4% relative density at 1200°C for 5 h in air, which is about 200°C lower than that without Zn dopant. By fabricating thin membrane BCZYZn electrolyte (about 30 µm in thickness) on NiO-BCZYZn anode support, PCMFCs were assembled and tested by selecting stable BSZF perovskite cathode. An open-circuit potential of 1.00 V, a maximum power density of 236 mWcm-2, and a low polarization resistance of the electrodes of 0.17 O cm2 were achieved at 700°C. This investigation indicated that proton conducting electrolyte BCZYZn with BSZF perovskite cathode is a promising material system for the next generation solid oxide fuel cells. © 2008 Elsevier B.V. All rights reserved.

KW - Ba 0.5 Sr 0.5 Zn 0.2 Fe 0.8 O 3-δ

KW - BaCe 0.5 Zr 0.3 Y 0.16 Zn 0.04 O 3-δ

KW - Pechini method

KW - Solid oxide fuel cells

KW - Zn dopant

UR - https://www.scopus.com/pages/publications/48249155105

U2 - 10.1016/j.jpowsour.2008.05.075

DO - 10.1016/j.jpowsour.2008.05.075

M3 - Article

SN - 0378-7753

VL - 183

SP - 479

EP - 484

JO - Journal of Power Sources

JF - Journal of Power Sources

IS - 2

ER -

Stable, easily sintered BaCe_0.5Zr_0.3y _0.16Zn_0.04O_3-δ electrolyte-based protonic ceramic membrane fuel cells with Ba_0.5Sr_0.5Zn _0.2Fe_0.8O_3-δ perovskite cathode

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