Square planar and tetrahedral chromium(II) complexes; crystal structure determinations

D. C.  Bradley; M. B. Hursthouse; C. W. Newing; A. J. Welch

doi:10.1039/C39720000567

Square planar and tetrahedral chromium(II) complexes; crystal structure determinations

D. C. Bradley, M. B. Hursthouse^*, C. W. Newing, A. J. Welch

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

111 Citations (Scopus)

Abstract

The novel compound Cr[N(SiMe₃)₂]₂(THF)₂ has been prepared and characterised, and shown by X-ray crystal analysis to have the trans-square planar configuration; this contrasts with Cr(NO)[N(SiMe₃)₂]₃ which has been found to possess a pseudo-tetrahedral (C_3v) structure.

Original language	English
Pages (from-to)	567-568
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/C39720000567
Publication status	Published - 1972

ASJC Scopus subject areas

Molecular Medicine

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title = "Square planar and tetrahedral chromium(II) complexes; crystal structure determinations",

abstract = "The novel compound Cr[N(SiMe3)2]2(THF)2 has been prepared and characterised, and shown by X-ray crystal analysis to have the trans-square planar configuration; this contrasts with Cr(NO)[N(SiMe3)2]3 which has been found to possess a pseudo-tetrahedral (C3v) structure.",

author = "Bradley, {D. C.} and Hursthouse, {M. B.} and Newing, {C. W.} and Welch, {A. J.}",

year = "1972",

doi = "10.1039/C39720000567",

language = "English",

pages = "567--568",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "9",

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T1 - Square planar and tetrahedral chromium(II) complexes; crystal structure determinations

AU - Bradley, D. C.

AU - Hursthouse, M. B.

AU - Newing, C. W.

AU - Welch, A. J.

PY - 1972

Y1 - 1972

N2 - The novel compound Cr[N(SiMe3)2]2(THF)2 has been prepared and characterised, and shown by X-ray crystal analysis to have the trans-square planar configuration; this contrasts with Cr(NO)[N(SiMe3)2]3 which has been found to possess a pseudo-tetrahedral (C3v) structure.

AB - The novel compound Cr[N(SiMe3)2]2(THF)2 has been prepared and characterised, and shown by X-ray crystal analysis to have the trans-square planar configuration; this contrasts with Cr(NO)[N(SiMe3)2]3 which has been found to possess a pseudo-tetrahedral (C3v) structure.

UR - http://www.scopus.com/inward/record.url?scp=37049140685&partnerID=8YFLogxK

U2 - 10.1039/C39720000567

DO - 10.1039/C39720000567

M3 - Article

AN - SCOPUS:37049140685

SN - 0022-4936

SP - 567

EP - 568

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 9

ER -

Square planar and tetrahedral chromium(II) complexes; crystal structure determinations

Abstract

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