Solvothermal synthesis and characterisation of new one-dimensional indium and gallium sulphides

[C10N4H26] 0.5[InS2] and [C10N4H 26]0.5[GaS2]

Paz Vaqueiro

Research output: Contribution to journalArticle

Abstract

Two new main group metal sulphides, [C10N4H 26]0.5[InS2] (1) and [C10N 4H26]0.5[GaS2] (2) have been prepared solvothermally in the presence of 1,4-bis(3-aminopropyl)piperazine and their crystal structures determined by single-crystal X-ray diffraction. Both compounds are isostructural and crystallise in the monoclinic space group P21/n (Z=4), with a=6.5628(5), b=11.2008(9), c=12.6611(9) Å and ß=94.410(4)° (wR=0.035) for compound (1) and a=6.1094(5), b=11.2469(9), c=12.7064(10) Å and ß=94.313(4)° (wR=0.021) for compound (2). The structure of [C10N4H26] 0.5[MS2] (M=In,Ga) consists of one-dimensional [MS 2]- chains which run parallel to the crystallographic a axis and are separated by diprotonated amine molecules. These materials represent the first example of solvothermally prepared one-dimensional gallium and indium sulphides. © 2005 Elsevier Inc. All rights reserved.

Original languageEnglish
Pages (from-to)302-307
Number of pages6
JournalJournal of Solid State Chemistry
Volume179
Issue number1
DOIs
Publication statusPublished - Jan 2006

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Gallium
Indium
Sulfides
Indium sulfide
Amines
Crystal structure
Metals
Single crystals
X ray diffraction
Molecules
1,4-bis(3-aminopropyl)piperazine

Keywords

  • Crystal structure
  • Gallium sulphides
  • Indium sulphides
  • Solvothermal synthesis

Cite this

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title = "Solvothermal synthesis and characterisation of new one-dimensional indium and gallium sulphides: [C10N4H26] 0.5[InS2] and [C10N4H 26]0.5[GaS2]",
abstract = "Two new main group metal sulphides, [C10N4H 26]0.5[InS2] (1) and [C10N 4H26]0.5[GaS2] (2) have been prepared solvothermally in the presence of 1,4-bis(3-aminopropyl)piperazine and their crystal structures determined by single-crystal X-ray diffraction. Both compounds are isostructural and crystallise in the monoclinic space group P21/n (Z=4), with a=6.5628(5), b=11.2008(9), c=12.6611(9) {\AA} and {\ss}=94.410(4)° (wR=0.035) for compound (1) and a=6.1094(5), b=11.2469(9), c=12.7064(10) {\AA} and {\ss}=94.313(4)° (wR=0.021) for compound (2). The structure of [C10N4H26] 0.5[MS2] (M=In,Ga) consists of one-dimensional [MS 2]- chains which run parallel to the crystallographic a axis and are separated by diprotonated amine molecules. These materials represent the first example of solvothermally prepared one-dimensional gallium and indium sulphides. {\circledC} 2005 Elsevier Inc. All rights reserved.",
keywords = "Crystal structure, Gallium sulphides, Indium sulphides, Solvothermal synthesis",
author = "Paz Vaqueiro",
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AU - Vaqueiro, Paz

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N2 - Two new main group metal sulphides, [C10N4H 26]0.5[InS2] (1) and [C10N 4H26]0.5[GaS2] (2) have been prepared solvothermally in the presence of 1,4-bis(3-aminopropyl)piperazine and their crystal structures determined by single-crystal X-ray diffraction. Both compounds are isostructural and crystallise in the monoclinic space group P21/n (Z=4), with a=6.5628(5), b=11.2008(9), c=12.6611(9) Å and ß=94.410(4)° (wR=0.035) for compound (1) and a=6.1094(5), b=11.2469(9), c=12.7064(10) Å and ß=94.313(4)° (wR=0.021) for compound (2). The structure of [C10N4H26] 0.5[MS2] (M=In,Ga) consists of one-dimensional [MS 2]- chains which run parallel to the crystallographic a axis and are separated by diprotonated amine molecules. These materials represent the first example of solvothermally prepared one-dimensional gallium and indium sulphides. © 2005 Elsevier Inc. All rights reserved.

AB - Two new main group metal sulphides, [C10N4H 26]0.5[InS2] (1) and [C10N 4H26]0.5[GaS2] (2) have been prepared solvothermally in the presence of 1,4-bis(3-aminopropyl)piperazine and their crystal structures determined by single-crystal X-ray diffraction. Both compounds are isostructural and crystallise in the monoclinic space group P21/n (Z=4), with a=6.5628(5), b=11.2008(9), c=12.6611(9) Å and ß=94.410(4)° (wR=0.035) for compound (1) and a=6.1094(5), b=11.2469(9), c=12.7064(10) Å and ß=94.313(4)° (wR=0.021) for compound (2). The structure of [C10N4H26] 0.5[MS2] (M=In,Ga) consists of one-dimensional [MS 2]- chains which run parallel to the crystallographic a axis and are separated by diprotonated amine molecules. These materials represent the first example of solvothermally prepared one-dimensional gallium and indium sulphides. © 2005 Elsevier Inc. All rights reserved.

KW - Crystal structure

KW - Gallium sulphides

KW - Indium sulphides

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