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Solution of the mean spherical approximation for polydisperse multi-Yukawa hard-sphere fluid mixture using orthogonal polynomial expansions

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Abstract

The Blum-Høye [J. Stat. Phys. 19 317 (1978)] solution of the mean spherical approximation for a multicomponent multi-Yukawa hard-sphere fluid is extended to a polydisperse multi-Yukawa hard-sphere fluid. Our extension is based on the application of the orthogonal polynomial expansion method of Lado [Phys. Rev. E 54, 4411 (1996)]. Closed form analytical expressions for the structural and thermodynamic properties of the model are presented. They are given in terms of the parameters that follow directly from the solution. By way of illustration the method of solution is applied to describe the thermodynamic properties of the one- and two-Yukawa versions of the model.

Original languageEnglish
Article number114509
JournalJournal of Chemical Physics
Volume124
Issue number11
DOIs
Publication statusPublished - 21 Mar 2006

Keywords

  • Phase transitions
  • Thermal effects
  • Thermodynamic properties
  • Integral transforms
  • Interatomic potentials
  • Elementary particle interactions
  • Electrolytes
  • Potential energy barrier
  • Statistical mechanics models
  • Classical statistical mechanics

ASJC Scopus subject areas

  • General Physics and Astronomy
  • Physical and Theoretical Chemistry

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