Solid state studies of some nitrosoaromatic iron carbonyls

M. Cameron, B. G. Gowenlock, R. V. Parish, G. Vasapollo

Research output: Contribution to journalArticle

Abstract

Mössbauer spectroscopic studies of a tricarbonyl-(nitrosobenzene)iron compound and two dicarbonyl- (nitrosobenzene)triphenyl-phosphineiron compounds have shown that these compounds possess similar structures and are dimeric in character. Solid state 13C NMR spectroscopy shows that although in such compounds the NO bond length approaches that characteristic of a single bond, the large ipso chemical shift of the NO group is only slightly diminished. Other consequences of coordination for the structure of the C-nitroso ligand are also discussed. © 1994.

Original languageEnglish
Pages (from-to)227-230
Number of pages4
JournalJournal of Organometallic Chemistry
Volume482
Issue number1-2
Publication statusPublished - 29 Nov 1994

Keywords

  • Carbonyl
  • Iron
  • Mössbauer spectra
  • Nitroso compound
  • Nuclear magnetic resonance
  • Phosphine

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    Cameron, M., Gowenlock, B. G., Parish, R. V., & Vasapollo, G. (1994). Solid state studies of some nitrosoaromatic iron carbonyls. Journal of Organometallic Chemistry, 482(1-2), 227-230.