Sodium intercalation into the defect garnets Fe2(MoO4)3 and Fe2(WO4)3

P. G. Bruce, G. Miln

Research output: Contribution to journalArticle

Abstract

Sodium has been reversibly intercalated into the defect garnets Fe2(MoO4)3 and Fe2(WO4)3, yielding two new compounds, Na2Fe2(MoO4)3 and Na2Fe2(WO4)3, which retain the monoclinic symmetry of the parent compounds but with expanded unit cells. The lattice parameters for Na2Fe2(MoO4)3 are a = 16.09 Å, b = 9.507 Å, c = 18.64 Å, ß = 125.27° and for Na2Fe2(WO4)3 a = 16.16 Å, b = 9.582 Å, c = 18.80 Å, ß = 125.56°. At low sodium contents a narrow solid solution range is evident for both the tungstate and the molybdate, the structure of which is based on the parent compound. © 1990.

Original languageEnglish
Pages (from-to)162-166
Number of pages5
JournalJournal of Solid State Chemistry
Volume89
Issue number1
Publication statusPublished - Nov 1990

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Garnets
Intercalation
Sodium
Defects
Lattice constants
Solid solutions
tungstate
molybdate

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Bruce, P. G. ; Miln, G. / Sodium intercalation into the defect garnets Fe2(MoO4)3 and Fe2(WO4)3. In: Journal of Solid State Chemistry. 1990 ; Vol. 89, No. 1. pp. 162-166.
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abstract = "Sodium has been reversibly intercalated into the defect garnets Fe2(MoO4)3 and Fe2(WO4)3, yielding two new compounds, Na2Fe2(MoO4)3 and Na2Fe2(WO4)3, which retain the monoclinic symmetry of the parent compounds but with expanded unit cells. The lattice parameters for Na2Fe2(MoO4)3 are a = 16.09 {\AA}, b = 9.507 {\AA}, c = 18.64 {\AA}, {\ss} = 125.27° and for Na2Fe2(WO4)3 a = 16.16 {\AA}, b = 9.582 {\AA}, c = 18.80 {\AA}, {\ss} = 125.56°. At low sodium contents a narrow solid solution range is evident for both the tungstate and the molybdate, the structure of which is based on the parent compound. {\circledC} 1990.",
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Sodium intercalation into the defect garnets Fe2(MoO4)3 and Fe2(WO4)3. / Bruce, P. G.; Miln, G.

In: Journal of Solid State Chemistry, Vol. 89, No. 1, 11.1990, p. 162-166.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Sodium intercalation into the defect garnets Fe2(MoO4)3 and Fe2(WO4)3

AU - Bruce, P. G.

AU - Miln, G.

PY - 1990/11

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N2 - Sodium has been reversibly intercalated into the defect garnets Fe2(MoO4)3 and Fe2(WO4)3, yielding two new compounds, Na2Fe2(MoO4)3 and Na2Fe2(WO4)3, which retain the monoclinic symmetry of the parent compounds but with expanded unit cells. The lattice parameters for Na2Fe2(MoO4)3 are a = 16.09 Å, b = 9.507 Å, c = 18.64 Å, ß = 125.27° and for Na2Fe2(WO4)3 a = 16.16 Å, b = 9.582 Å, c = 18.80 Å, ß = 125.56°. At low sodium contents a narrow solid solution range is evident for both the tungstate and the molybdate, the structure of which is based on the parent compound. © 1990.

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