Abstract
Two Rh complexes of the phosphinophosphinine ligand 2-PPh2-3-Me-6-SiMe3-C5H2P (1) were prepared: dinuclear trans-[Rh(CO)(Cl)(μ-1)}2] (2) and chelating [Rh(1)(COD)][BArF4] (3). Despite the widespread use of Rh catalysts for the hydroboration of alkenes, 3 is reported to be the first Rh catalyst for ketone and ketimine hydroboration, with high activity observed at 0.1 mol% loading.
| Original language | English |
|---|---|
| Pages (from-to) | 5482-5485 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 54 |
| Issue number | 43 |
| Early online date | 14 May 2018 |
| DOIs | |
| Publication status | Published - 28 May 2018 |
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Additional data supporting the publication of: Small bite-angle phosphinophosphinine ligands enable rhodium catalysed hydroboration of carbonyls
Mansell, S. M. (Creator) & Newland, R. (Creator), Heriot-Watt University, 12 Apr 2018
DOI: 10.17861/14c23fe6-bc65-4806-ba5e-63642a6ad3e9
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Profiles
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Stephen M. Mansell
- School of Engineering & Physical Sciences - Assistant Professor
- School of Engineering & Physical Sciences, Institute of Chemical Sciences - Assistant Professor
Person: Academic (Research & Teaching)