Simple and Versatile Selective Synthesis of Neutral and Cationic Copper(I) N-Heterocyclic Carbene Complexes Using an Electrochemical Procedure

Benjamin R. M. Lake; Emma K. Bullough; Thomas J. Williams; Adrian C. Whitwood; Marc A. Little; Charlotte E. Willans

doi:10.1039/c2cc30862b

Simple and Versatile Selective Synthesis of Neutral and Cationic Copper(I) N-Heterocyclic Carbene Complexes Using an Electrochemical Procedure

Benjamin R. M. Lake
, Emma K. Bullough
, Thomas J. Williams
, Adrian C. Whitwood
, Marc A. Little
, Charlotte E. Willans^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

48 Citations (Scopus)

Abstract

An electrochemical approach for the preparation of copper(i) N-heterocyclic carbene complexes has been developed to include a diverse range of ligand precursors. Importantly, the method is effective for a ligand precursor that contains several acidic protons and for which traditional methods of carbene formation are not suitable.

Original language	English
Pages (from-to)	4887-4889
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	40
DOIs	https://doi.org/10.1039/c2cc30862b
Publication status	Published - 18 May 2012

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c2cc30862b

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title = "Simple and Versatile Selective Synthesis of Neutral and Cationic Copper(I) N-Heterocyclic Carbene Complexes Using an Electrochemical Procedure",

abstract = "An electrochemical approach for the preparation of copper(i) N-heterocyclic carbene complexes has been developed to include a diverse range of ligand precursors. Importantly, the method is effective for a ligand precursor that contains several acidic protons and for which traditional methods of carbene formation are not suitable.",

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AU - Lake, Benjamin R. M.

AU - Bullough, Emma K.

AU - Williams, Thomas J.

AU - Whitwood, Adrian C.

AU - Little, Marc A.

AU - Willans, Charlotte E.

PY - 2012/5/18

Y1 - 2012/5/18

N2 - An electrochemical approach for the preparation of copper(i) N-heterocyclic carbene complexes has been developed to include a diverse range of ligand precursors. Importantly, the method is effective for a ligand precursor that contains several acidic protons and for which traditional methods of carbene formation are not suitable.

AB - An electrochemical approach for the preparation of copper(i) N-heterocyclic carbene complexes has been developed to include a diverse range of ligand precursors. Importantly, the method is effective for a ligand precursor that contains several acidic protons and for which traditional methods of carbene formation are not suitable.

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U2 - 10.1039/c2cc30862b

DO - 10.1039/c2cc30862b

M3 - Article

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JO - Chemical Communications

JF - Chemical Communications

IS - 40

ER -

Simple and Versatile Selective Synthesis of Neutral and Cationic Copper(I) N-Heterocyclic Carbene Complexes Using an Electrochemical Procedure

Abstract

ASJC Scopus subject areas

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