Self-organization of spheroidal molecular assemblies in polar solvents

Thomas Grawe; Thomas Schrader; Marion Gurrath; Arno Kraft; Frank Osterod

Self-organization of spheroidal molecular assemblies in polar solvents

Thomas Grawe
, Thomas Schrader
, Marion Gurrath
, Arno Kraft
, Frank Osterod

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

(formula presented) We report a number of 1:1 noncovalent complexes composed of a symmetrical trisphosphonate and various symmetrical trisammonium or trisamidinium compounds. The spheroidal complexes show high thermodynamic stability, with association constants K_a reaching 10⁶ M^-1 in methanol and in some cases even exceeding 10³ M^-1 in water. The observed K_a values correlate well with the different degree of preorganization of the complexation partners.

Original language	English
Pages (from-to)	29-32
Number of pages	4
Journal	Organic Letters
Volume	2
Issue number	1
Publication status	Published - Jan 2000

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title = "Self-organization of spheroidal molecular assemblies in polar solvents",

abstract = "(formula presented) We report a number of 1:1 noncovalent complexes composed of a symmetrical trisphosphonate and various symmetrical trisammonium or trisamidinium compounds. The spheroidal complexes show high thermodynamic stability, with association constants Ka reaching 106 M-1 in methanol and in some cases even exceeding 103 M-1 in water. The observed Ka values correlate well with the different degree of preorganization of the complexation partners.",

author = "Thomas Grawe and Thomas Schrader and Marion Gurrath and Arno Kraft and Frank Osterod",

year = "2000",

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T1 - Self-organization of spheroidal molecular assemblies in polar solvents

AU - Grawe, Thomas

AU - Schrader, Thomas

AU - Gurrath, Marion

AU - Kraft, Arno

AU - Osterod, Frank

PY - 2000/1

Y1 - 2000/1

N2 - (formula presented) We report a number of 1:1 noncovalent complexes composed of a symmetrical trisphosphonate and various symmetrical trisammonium or trisamidinium compounds. The spheroidal complexes show high thermodynamic stability, with association constants Ka reaching 106 M-1 in methanol and in some cases even exceeding 103 M-1 in water. The observed Ka values correlate well with the different degree of preorganization of the complexation partners.

AB - (formula presented) We report a number of 1:1 noncovalent complexes composed of a symmetrical trisphosphonate and various symmetrical trisammonium or trisamidinium compounds. The spheroidal complexes show high thermodynamic stability, with association constants Ka reaching 106 M-1 in methanol and in some cases even exceeding 103 M-1 in water. The observed Ka values correlate well with the different degree of preorganization of the complexation partners.

UR - https://www.scopus.com/pages/publications/0002639416

M3 - Article

SN - 1523-7052

VL - 2

SP - 29

EP - 32

JO - Organic Letters

JF - Organic Letters

IS - 1

ER -

Self-organization of spheroidal molecular assemblies in polar solvents

Abstract

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