Self-assembly of molecular capsules in polar solvents

Reza Zadmard, Thomas Schrader, Thomas Grawe, Arno Kraft

Research output: Contribution to journalArticle

60 Citations (Scopus)

Abstract

We present a novel type of molecular capsule formed by self-organization of calix[4]arenes with several oppositely charged functional groups located at their upper rims. In highly polar solvents, the complementary half-spheres form stable 1:1 complexes with association constants of up to 7 × 105 M-1 in methanol. The cavity inside the capsules is large enough for the inclusion of small aliphatic or (hetero)aromatic guest molecules.

Original languageEnglish
Pages (from-to)1687-1690
Number of pages4
JournalOrganic Letters
Volume4
Issue number10
DOIs
Publication statusPublished - 16 May 2002

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