Selective Production of Carvacrol from Carvone over Supported Pd Catalysts

Pedro Benavente, Fernando Cardenas-Lizana, Mark A. Keane

Research output: Contribution to journalArticle

3 Citations (Scopus)
63 Downloads (Pure)

Abstract

The selective conversion of biomass-derived carvone in H2 was studied over (Al2O3, C and CeO2) supported Pd (mean size 2.8–3.0 nm), taking bulk Pd as benchmark. 100% carvacrol yield was achieved over Pd/Al2O3, Pd/C and bulk Pd at an inlet H2/carvone = 1/6, with appreciably higher rates for the supported catalysts. Carveol formation over Pd/CeO2 was attributed to single bondCdouble bond; length as m-dashO activation at surface oxygen vacancies (confirmed by O2 titration) generated during TPR. Carvotanacetone and carvomenthone formation were observed at H2/carvone > 1/6.
Original languageEnglish
Pages (from-to)37–40
Number of pages4
JournalCatalysis Communications
Volume96
Early online date29 Mar 2017
DOIs
Publication statusPublished - Jun 2017

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