Segregation behaviour of deuterated poly(styrene-block-methyl methacrylate) diblock copolymer in the presence of poly(methyl methacrylate) homopolymer

D. G. Bucknall; J. S. Higgins; J. Penfold; S. Rostami

doi:10.1016/0032-3861(93)90534-H

Segregation behaviour of deuterated poly(styrene-block-methyl methacrylate) diblock copolymer in the presence of poly(methyl methacrylate) homopolymer

D. G. Bucknall, J. S. Higgins^*, J. Penfold, S. Rostami

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Copolymer segregation behaviour has been studied using the technique of neutron critical reflection from layered samples. Surface segregation occurs due to location at the air/polymer interface of a copolymer microphase-segregated layer. Similar microphase segregation by the copolymer occurs during mutual diffusion with the homopolymer. By comparison with theoretical predictions, this segregation is shown to exhibit behaviour characteristic of end-tethered polymer brushes.

Original language	English
Pages (from-to)	451-458
Number of pages	8
Journal	Polymer
Volume	34
Issue number	3
DOIs	https://doi.org/10.1016/0032-3861(93)90534-H
Publication status	Published - 1993

Keywords

deuterated copolymer
diblock copolymer
micelle formation
neutron reflection
poly(methyl methacrylate)
polystyrene
surface segregation

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics

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10.1016/0032-3861(93)90534-H

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title = "Segregation behaviour of deuterated poly(styrene-block-methyl methacrylate) diblock copolymer in the presence of poly(methyl methacrylate) homopolymer",

abstract = "Copolymer segregation behaviour has been studied using the technique of neutron critical reflection from layered samples. Surface segregation occurs due to location at the air/polymer interface of a copolymer microphase-segregated layer. Similar microphase segregation by the copolymer occurs during mutual diffusion with the homopolymer. By comparison with theoretical predictions, this segregation is shown to exhibit behaviour characteristic of end-tethered polymer brushes.",

keywords = "deuterated copolymer, diblock copolymer, micelle formation, neutron reflection, poly(methyl methacrylate), polystyrene, surface segregation",

author = "Bucknall, \{D. G.\} and Higgins, \{J. S.\} and J. Penfold and S. Rostami",

year = "1993",

doi = "10.1016/0032-3861(93)90534-H",

language = "English",

volume = "34",

pages = "451--458",

journal = "Polymer",

issn = "0032-3861",

publisher = "Elsevier B.V.",

number = "3",

}

TY - JOUR

T1 - Segregation behaviour of deuterated poly(styrene-block-methyl methacrylate) diblock copolymer in the presence of poly(methyl methacrylate) homopolymer

AU - Bucknall, D. G.

AU - Higgins, J. S.

AU - Penfold, J.

AU - Rostami, S.

PY - 1993

Y1 - 1993

N2 - Copolymer segregation behaviour has been studied using the technique of neutron critical reflection from layered samples. Surface segregation occurs due to location at the air/polymer interface of a copolymer microphase-segregated layer. Similar microphase segregation by the copolymer occurs during mutual diffusion with the homopolymer. By comparison with theoretical predictions, this segregation is shown to exhibit behaviour characteristic of end-tethered polymer brushes.

AB - Copolymer segregation behaviour has been studied using the technique of neutron critical reflection from layered samples. Surface segregation occurs due to location at the air/polymer interface of a copolymer microphase-segregated layer. Similar microphase segregation by the copolymer occurs during mutual diffusion with the homopolymer. By comparison with theoretical predictions, this segregation is shown to exhibit behaviour characteristic of end-tethered polymer brushes.

KW - deuterated copolymer

KW - diblock copolymer

KW - micelle formation

KW - neutron reflection

KW - poly(methyl methacrylate)

KW - polystyrene

KW - surface segregation

UR - https://www.scopus.com/pages/publications/0027815463

U2 - 10.1016/0032-3861(93)90534-H

DO - 10.1016/0032-3861(93)90534-H

M3 - Article

AN - SCOPUS:0027815463

SN - 0032-3861

VL - 34

SP - 451

EP - 458

JO - Polymer

JF - Polymer

IS - 3

ER -

Segregation behaviour of deuterated poly(styrene-block-methyl methacrylate) diblock copolymer in the presence of poly(methyl methacrylate) homopolymer

Abstract

Keywords

ASJC Scopus subject areas

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