Salt formation affects the conformational and assembly properties of p-carboxylatocalix[4]arenes

Stuart Kennedy; Christine M. Beavers; Simon J. Teat; Scott J. Dalgarno

doi:10.1039/c3ce42523a

Salt formation affects the conformational and assembly properties of p-carboxylatocalix[4]arenes

Stuart Kennedy^*
, Christine M. Beavers
, Simon J. Teat
, Scott J. Dalgarno

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The conformational properties and self-assembly behaviour of the p-carboxylatocalix[4]arenes, when in the presence of a pyridine template, are well understood. Salt formation with these molecules, a process driven by the introduction of an amino group to the 2-position of the pyridine template, has dramatic consequences on both building block conformation and the resulting self-assembly.

Original language	English
Pages (from-to)	3712-3717
Number of pages	6
Journal	CrystEngComm
Volume	16
Issue number	18
DOIs	https://doi.org/10.1039/c3ce42523a
Publication status	Published - 2014

Keywords

METAL-ORGANIC FRAMEWORKS
CALIXARENE NANOTUBES
POROUS MATERIALS
CRYSTALS

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10.1039/c3ce42523a

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title = "Salt formation affects the conformational and assembly properties of p-carboxylatocalix[4]arenes",

abstract = "The conformational properties and self-assembly behaviour of the p-carboxylatocalix[4]arenes, when in the presence of a pyridine template, are well understood. Salt formation with these molecules, a process driven by the introduction of an amino group to the 2-position of the pyridine template, has dramatic consequences on both building block conformation and the resulting self-assembly.",

keywords = "METAL-ORGANIC FRAMEWORKS, CALIXARENE NANOTUBES, POROUS MATERIALS, CRYSTALS",

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year = "2014",

doi = "10.1039/c3ce42523a",

language = "English",

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pages = "3712--3717",

journal = "CrystEngComm",

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publisher = "Royal Society of Chemistry",

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AU - Kennedy, Stuart

AU - Beavers, Christine M.

AU - Teat, Simon J.

AU - Dalgarno, Scott J.

PY - 2014

Y1 - 2014

N2 - The conformational properties and self-assembly behaviour of the p-carboxylatocalix[4]arenes, when in the presence of a pyridine template, are well understood. Salt formation with these molecules, a process driven by the introduction of an amino group to the 2-position of the pyridine template, has dramatic consequences on both building block conformation and the resulting self-assembly.

AB - The conformational properties and self-assembly behaviour of the p-carboxylatocalix[4]arenes, when in the presence of a pyridine template, are well understood. Salt formation with these molecules, a process driven by the introduction of an amino group to the 2-position of the pyridine template, has dramatic consequences on both building block conformation and the resulting self-assembly.

KW - METAL-ORGANIC FRAMEWORKS

KW - CALIXARENE NANOTUBES

KW - POROUS MATERIALS

KW - CRYSTALS

U2 - 10.1039/c3ce42523a

DO - 10.1039/c3ce42523a

M3 - Article

SN - 1466-8033

VL - 16

SP - 3712

EP - 3717

JO - CrystEngComm

JF - CrystEngComm

IS - 18

ER -

Salt formation affects the conformational and assembly properties of p-carboxylatocalix[4]arenes

Abstract

Keywords

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