Robust mesocellular carbon foam counter electrode for quantum-dot sensitized solar cells

P. Sudhagar; Easwaramoorthi Ramasamy; Woo Hyung Cho; Jinwoo Lee; Yong Soo Kang

doi:10.1016/j.elecom.2010.11.006

Robust mesocellular carbon foam counter electrode for quantum-dot sensitized solar cells

P. Sudhagar, Easwaramoorthi Ramasamy, Woo Hyung Cho, Jinwoo Lee^*, Yong Soo Kang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

63 Citations (Scopus)

Abstract

Mesocellular carbon foams (MSU-F-Cs) with a high surface area (911 m²g^-1) and large pores (~ 25 nm) have been used as counter electrodes for CdS/CdSe quantum-dot sensitized solar cells (QD-SSCs). Under 1 sun illumination, the MSU-F-C counter electrode QD-SSC shows a maximum energy conversion efficiency of 1.75%, which is much higher than that of those employing conventional Pt (1.22%) or commercial carbon (0.94%) counter electrodes. Electrochemical impedance spectroscopy analysis shows that the large pores and high surface area of MSU-FC improve the catalytic activity of the counter electrode in polysulfide redox electrolyte.

Original language	English
Pages (from-to)	34-37
Number of pages	4
Journal	Electrochemistry Communications
Volume	13
Issue number	1
DOIs	https://doi.org/10.1016/j.elecom.2010.11.006
Publication status	Published - Jan 2011

Keywords

Counter electrode
Mesocellular carbon foam
Quantum-dot solar cell

ASJC Scopus subject areas

Electrochemistry

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10.1016/j.elecom.2010.11.006

Cite this

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title = "Robust mesocellular carbon foam counter electrode for quantum-dot sensitized solar cells",

abstract = "Mesocellular carbon foams (MSU-F-Cs) with a high surface area (911 m2g-1) and large pores (\textasciitilde{} 25 nm) have been used as counter electrodes for CdS/CdSe quantum-dot sensitized solar cells (QD-SSCs). Under 1 sun illumination, the MSU-F-C counter electrode QD-SSC shows a maximum energy conversion efficiency of 1.75\%, which is much higher than that of those employing conventional Pt (1.22\%) or commercial carbon (0.94\%) counter electrodes. Electrochemical impedance spectroscopy analysis shows that the large pores and high surface area of MSU-FC improve the catalytic activity of the counter electrode in polysulfide redox electrolyte.",

keywords = "Counter electrode, Mesocellular carbon foam, Quantum-dot solar cell",

author = "P. Sudhagar and Easwaramoorthi Ramasamy and Cho, \{Woo Hyung\} and Jinwoo Lee and Kang, \{Yong Soo\}",

note = "Funding Information: This work was supported by the Engineering Research Center Program ( 2010-0001842 ) through a National Research Foundation of Korea (NRF) grant funded by the Ministry of Education, Science and Technology, Korea. Also, this work was supported by the National Research Foundation of Korea Grant funded by the Korean Government ( 2009-0064640 ).",

year = "2011",

month = jan,

doi = "10.1016/j.elecom.2010.11.006",

language = "English",

volume = "13",

pages = "34--37",

journal = "Electrochemistry Communications",

issn = "1388-2481",

publisher = "Elsevier Inc.",

number = "1",

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TY - JOUR

T1 - Robust mesocellular carbon foam counter electrode for quantum-dot sensitized solar cells

AU - Sudhagar, P.

AU - Ramasamy, Easwaramoorthi

AU - Cho, Woo Hyung

AU - Lee, Jinwoo

AU - Kang, Yong Soo

N1 - Funding Information: This work was supported by the Engineering Research Center Program ( 2010-0001842 ) through a National Research Foundation of Korea (NRF) grant funded by the Ministry of Education, Science and Technology, Korea. Also, this work was supported by the National Research Foundation of Korea Grant funded by the Korean Government ( 2009-0064640 ).

PY - 2011/1

Y1 - 2011/1

N2 - Mesocellular carbon foams (MSU-F-Cs) with a high surface area (911 m2g-1) and large pores (~ 25 nm) have been used as counter electrodes for CdS/CdSe quantum-dot sensitized solar cells (QD-SSCs). Under 1 sun illumination, the MSU-F-C counter electrode QD-SSC shows a maximum energy conversion efficiency of 1.75%, which is much higher than that of those employing conventional Pt (1.22%) or commercial carbon (0.94%) counter electrodes. Electrochemical impedance spectroscopy analysis shows that the large pores and high surface area of MSU-FC improve the catalytic activity of the counter electrode in polysulfide redox electrolyte.

AB - Mesocellular carbon foams (MSU-F-Cs) with a high surface area (911 m2g-1) and large pores (~ 25 nm) have been used as counter electrodes for CdS/CdSe quantum-dot sensitized solar cells (QD-SSCs). Under 1 sun illumination, the MSU-F-C counter electrode QD-SSC shows a maximum energy conversion efficiency of 1.75%, which is much higher than that of those employing conventional Pt (1.22%) or commercial carbon (0.94%) counter electrodes. Electrochemical impedance spectroscopy analysis shows that the large pores and high surface area of MSU-FC improve the catalytic activity of the counter electrode in polysulfide redox electrolyte.

KW - Counter electrode

KW - Mesocellular carbon foam

KW - Quantum-dot solar cell

UR - https://www.scopus.com/pages/publications/78650555644

U2 - 10.1016/j.elecom.2010.11.006

DO - 10.1016/j.elecom.2010.11.006

M3 - Article

AN - SCOPUS:78650555644

SN - 1388-2481

VL - 13

SP - 34

EP - 37

JO - Electrochemistry Communications

JF - Electrochemistry Communications

IS - 1

ER -

Robust mesocellular carbon foam counter electrode for quantum-dot sensitized solar cells

Abstract

Keywords

ASJC Scopus subject areas

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