Reversible syntheses of cyclopentadienylrhodium-triruthenium cluster complexes; crystal and molecular structure of (η-C5Me 5)RhRu3(μ-H)4(CO)9

W. Edward Lindsell; Carolyn B. Knobler; Herbert D. Kaesz

Reversible syntheses of cyclopentadienylrhodium-triruthenium cluster complexes; crystal and molecular structure of (η-C₅Me ₅)RhRu₃(μ-H)₄(CO)₉

W. Edward Lindsell, Carolyn B. Knobler, Herbert D. Kaesz

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The mixed metal complexes cpRhRu₃(µ-H)₂(µ-CO) (CO)₉ (cp = ?-C₅H₅ or ?-C ₅Me₅) and (?-C₅Me₅)RhRu ₃(µ-H)₄(CO)₉ (in which the four bridging hydrogen atoms have been located in an X-ray structure determination) are formed when H₂ is bubbled through solutions of Ru₃(CO) ₁₂ and the respective cpRh(CO)₂ at 70-90 °C but, under 1 atm CO at 25 °C, are easily disrupted into the starting materials, which are obtained with complete ¹³C-enrichment under 1 atm ¹³CO.

Original language	English
Pages (from-to)	1171-1172
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	17
Publication status	Published - 1985

Cite this

@article{5e78363d01724e31bd3ed6ea14c7497d,

title = "Reversible syntheses of cyclopentadienylrhodium-triruthenium cluster complexes; crystal and molecular structure of (η-C5Me 5)RhRu3(μ-H)4(CO)9",

abstract = "The mixed metal complexes cpRhRu3(µ-H)2(µ-CO) (CO)9 (cp = ?-C5H5 or ?-C 5Me5) and (?-C5Me5)RhRu 3(µ-H)4(CO)9 (in which the four bridging hydrogen atoms have been located in an X-ray structure determination) are formed when H2 is bubbled through solutions of Ru3(CO) 12 and the respective cpRh(CO)2 at 70-90 °C but, under 1 atm CO at 25 °C, are easily disrupted into the starting materials, which are obtained with complete 13C-enrichment under 1 atm 13CO.",

author = "Lindsell, {W. Edward} and Knobler, {Carolyn B.} and Kaesz, {Herbert D.}",

year = "1985",

language = "English",

pages = "1171--1172",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "17",

}

TY - JOUR

T1 - Reversible syntheses of cyclopentadienylrhodium-triruthenium cluster complexes; crystal and molecular structure of (η-C5Me 5)RhRu3(μ-H)4(CO)9

AU - Lindsell, W. Edward

AU - Knobler, Carolyn B.

AU - Kaesz, Herbert D.

PY - 1985

Y1 - 1985

N2 - The mixed metal complexes cpRhRu3(µ-H)2(µ-CO) (CO)9 (cp = ?-C5H5 or ?-C 5Me5) and (?-C5Me5)RhRu 3(µ-H)4(CO)9 (in which the four bridging hydrogen atoms have been located in an X-ray structure determination) are formed when H2 is bubbled through solutions of Ru3(CO) 12 and the respective cpRh(CO)2 at 70-90 °C but, under 1 atm CO at 25 °C, are easily disrupted into the starting materials, which are obtained with complete 13C-enrichment under 1 atm 13CO.

AB - The mixed metal complexes cpRhRu3(µ-H)2(µ-CO) (CO)9 (cp = ?-C5H5 or ?-C 5Me5) and (?-C5Me5)RhRu 3(µ-H)4(CO)9 (in which the four bridging hydrogen atoms have been located in an X-ray structure determination) are formed when H2 is bubbled through solutions of Ru3(CO) 12 and the respective cpRh(CO)2 at 70-90 °C but, under 1 atm CO at 25 °C, are easily disrupted into the starting materials, which are obtained with complete 13C-enrichment under 1 atm 13CO.

M3 - Article

SN - 0022-4936

SP - 1171

EP - 1172

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 17

ER -

Reversible syntheses of cyclopentadienylrhodium-triruthenium cluster complexes; crystal and molecular structure of (η-C5Me 5)RhRu3(μ-H)4(CO)9

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Reversible syntheses of cyclopentadienylrhodium-triruthenium cluster complexes; crystal and molecular structure of (η-C₅Me ₅)RhRu₃(μ-H)₄(CO)₉