Abstract
[Chemical equation presented] A highly regioselective method towards tertiary allylic ethers via gold(l)-catalyzed intermolecular hydroalkoxylation of alienes is disclosed. Preventing subsequent isomerizatlon of the tertiary allylic ether products to primary allylic ethers appears to be the key to achieving high regioselectivities. © 2010 American Chemical Society.
| Original language | English |
|---|---|
| Pages (from-to) | 484-487 |
| Number of pages | 4 |
| Journal | Organic Letters |
| Volume | 12 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - 5 Feb 2010 |
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Hadfield, M. S., & Lee, A. L. (2010). Regioselective synthesis of tert-allylic ethers via gold(l)-catalyzed intermolecular hydroalkoxylation of allenes. Organic Letters, 12(3), 484-487. https://doi.org/10.1021/ol902675k