Regioselective synthesis of tert-allylic ethers via gold(l)-catalyzed intermolecular hydroalkoxylation of allenes

Maximillian S. Hadfield; Ai L. Lee

doi:10.1021/ol902675k

Regioselective synthesis of tert-allylic ethers via gold(l)-catalyzed intermolecular hydroalkoxylation of allenes

Maximillian S. Hadfield, Ai L. Lee

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article

Abstract

[Chemical equation presented] A highly regioselective method towards tertiary allylic ethers via gold(l)-catalyzed intermolecular hydroalkoxylation of alienes is disclosed. Preventing subsequent isomerizatlon of the tertiary allylic ether products to primary allylic ethers appears to be the key to achieving high regioselectivities. © 2010 American Chemical Society.

Original language	English
Pages (from-to)	484-487
Number of pages	4
Journal	Organic Letters
Volume	12
Issue number	3
DOIs	https://doi.org/10.1021/ol902675k
Publication status	Published - 5 Feb 2010

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Hadfield, M. S., & Lee, A. L. (2010). Regioselective synthesis of tert-allylic ethers via gold(l)-catalyzed intermolecular hydroalkoxylation of allenes. Organic Letters, 12(3), 484-487. https://doi.org/10.1021/ol902675k

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abstract = "[Chemical equation presented] A highly regioselective method towards tertiary allylic ethers via gold(l)-catalyzed intermolecular hydroalkoxylation of alienes is disclosed. Preventing subsequent isomerizatlon of the tertiary allylic ether products to primary allylic ethers appears to be the key to achieving high regioselectivities. {\circledC} 2010 American Chemical Society.",

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AB - [Chemical equation presented] A highly regioselective method towards tertiary allylic ethers via gold(l)-catalyzed intermolecular hydroalkoxylation of alienes is disclosed. Preventing subsequent isomerizatlon of the tertiary allylic ether products to primary allylic ethers appears to be the key to achieving high regioselectivities. © 2010 American Chemical Society.

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10.1021/ol902675k