Regioselective synthesis of tert-allylic ethers via gold(l)-catalyzed intermolecular hydroalkoxylation of allenes

Maximillian S. Hadfield; Ai L. Lee

doi:10.1021/ol902675k

Regioselective synthesis of tert-allylic ethers via gold(l)-catalyzed intermolecular hydroalkoxylation of allenes

Maximillian S. Hadfield, Ai L. Lee

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

60 Citations (Scopus)

Abstract

[Chemical equation presented] A highly regioselective method towards tertiary allylic ethers via gold(l)-catalyzed intermolecular hydroalkoxylation of alienes is disclosed. Preventing subsequent isomerizatlon of the tertiary allylic ether products to primary allylic ethers appears to be the key to achieving high regioselectivities. © 2010 American Chemical Society.

Original language	English
Pages (from-to)	484-487
Number of pages	4
Journal	Organic Letters
Volume	12
Issue number	3
DOIs	https://doi.org/10.1021/ol902675k
Publication status	Published - 5 Feb 2010

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title = "Regioselective synthesis of tert-allylic ethers via gold(l)-catalyzed intermolecular hydroalkoxylation of allenes",

abstract = "[Chemical equation presented] A highly regioselective method towards tertiary allylic ethers via gold(l)-catalyzed intermolecular hydroalkoxylation of alienes is disclosed. Preventing subsequent isomerizatlon of the tertiary allylic ether products to primary allylic ethers appears to be the key to achieving high regioselectivities. {\textcopyright} 2010 American Chemical Society.",

author = "Hadfield, {Maximillian S.} and Lee, {Ai L.}",

year = "2010",

month = feb,

day = "5",

doi = "10.1021/ol902675k",

language = "English",

volume = "12",

pages = "484--487",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

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T1 - Regioselective synthesis of tert-allylic ethers via gold(l)-catalyzed intermolecular hydroalkoxylation of allenes

AU - Hadfield, Maximillian S.

AU - Lee, Ai L.

PY - 2010/2/5

Y1 - 2010/2/5

N2 - [Chemical equation presented] A highly regioselective method towards tertiary allylic ethers via gold(l)-catalyzed intermolecular hydroalkoxylation of alienes is disclosed. Preventing subsequent isomerizatlon of the tertiary allylic ether products to primary allylic ethers appears to be the key to achieving high regioselectivities. © 2010 American Chemical Society.

AB - [Chemical equation presented] A highly regioselective method towards tertiary allylic ethers via gold(l)-catalyzed intermolecular hydroalkoxylation of alienes is disclosed. Preventing subsequent isomerizatlon of the tertiary allylic ether products to primary allylic ethers appears to be the key to achieving high regioselectivities. © 2010 American Chemical Society.

U2 - 10.1021/ol902675k

DO - 10.1021/ol902675k

M3 - Article

VL - 12

SP - 484

EP - 487

JO - Organic Letters

JF - Organic Letters

SN - 1523-7060

IS - 3

ER -