Reductive Elimination at Carbon under Steric Control

Daniel R. Tolentino, Samuel E. Neale, Connie J. Isaac, Stuart A. MacGregor, Michael K. Whittlesey, Rodolphe Jazzar, Guy Bertrand

Research output: Contribution to journalArticle

10 Citations (Scopus)
6 Downloads (Pure)

Abstract

It has been previously demonstrated that stable singlet electrophilic carbenes can behave as metal surrogates in the activation of strong E-H bonds (E = H, B, N, Si, P), but it was believed that these activations only proceed through an irreversible activation barrier. Herein we show that, as is the case with transition metals, the steric environment can be used to promote reductive elimination at carbon centers.

Original languageEnglish
Pages (from-to)9823-9826
Number of pages4
JournalJournal of the American Chemical Society
Volume141
Issue number25
Early online date10 Jun 2019
DOIs
Publication statusPublished - 26 Jun 2019

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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