Reductive disproportionation of carbon dioxide at an iron(II) center

Olivia R. Allen; Scott J. Dalgarno; Leslie D. Field

doi:10.1021/om800408w

Reductive disproportionation of carbon dioxide at an iron(II) center

Olivia R. Allen
, Scott J. Dalgarno
, Leslie D. Field

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

The reaction of cis-Fe(dmpe)₂H₂ (1) with ¹³C-labeled carbon dioxide (CO₂) was investigated, and trans[Fe(dmpe)₂(CO)H] · [HCO₃] (5) was identified as a reaction byproduct. Both the carbonyl ligand and the bicarbonate anion are derived from CO₂, and this effectively constitutes a disproportionation of CO₂ to CO and CO₃^2-. trans-[Fe(dmpe)₂(CO)H].[HCO₃] (5) was characterized by crystallography and by NMR spectroscopy. © 2008 American Chemical Society.

Original language	English
Pages (from-to)	3328-3330
Number of pages	3
Journal	Organometallics
Volume	27
Issue number	14
DOIs	https://doi.org/10.1021/om800408w
Publication status	Published - 28 Jul 2008

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title = "Reductive disproportionation of carbon dioxide at an iron(II) center",

abstract = "The reaction of cis-Fe(dmpe)2H2 (1) with 13C-labeled carbon dioxide (CO2) was investigated, and trans[Fe(dmpe)2(CO)H] · [HCO3] (5) was identified as a reaction byproduct. Both the carbonyl ligand and the bicarbonate anion are derived from CO2, and this effectively constitutes a disproportionation of CO2 to CO and CO32-. trans-[Fe(dmpe)2(CO)H].[HCO3] (5) was characterized by crystallography and by NMR spectroscopy. {\textcopyright} 2008 American Chemical Society.",

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year = "2008",

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doi = "10.1021/om800408w",

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T1 - Reductive disproportionation of carbon dioxide at an iron(II) center

AU - Allen, Olivia R.

AU - Dalgarno, Scott J.

AU - Field, Leslie D.

PY - 2008/7/28

Y1 - 2008/7/28

N2 - The reaction of cis-Fe(dmpe)2H2 (1) with 13C-labeled carbon dioxide (CO2) was investigated, and trans[Fe(dmpe)2(CO)H] · [HCO3] (5) was identified as a reaction byproduct. Both the carbonyl ligand and the bicarbonate anion are derived from CO2, and this effectively constitutes a disproportionation of CO2 to CO and CO32-. trans-[Fe(dmpe)2(CO)H].[HCO3] (5) was characterized by crystallography and by NMR spectroscopy. © 2008 American Chemical Society.

AB - The reaction of cis-Fe(dmpe)2H2 (1) with 13C-labeled carbon dioxide (CO2) was investigated, and trans[Fe(dmpe)2(CO)H] · [HCO3] (5) was identified as a reaction byproduct. Both the carbonyl ligand and the bicarbonate anion are derived from CO2, and this effectively constitutes a disproportionation of CO2 to CO and CO32-. trans-[Fe(dmpe)2(CO)H].[HCO3] (5) was characterized by crystallography and by NMR spectroscopy. © 2008 American Chemical Society.

UR - https://www.scopus.com/pages/publications/49349116811

U2 - 10.1021/om800408w

DO - 10.1021/om800408w

M3 - Article

SN - 0276-7333

VL - 27

SP - 3328

EP - 3330

JO - Organometallics

JF - Organometallics

IS - 14

ER -

Reductive disproportionation of carbon dioxide at an iron(II) center

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