Abstract
The reaction of cis-Fe(dmpe)2H2 (1) with 13C-labeled carbon dioxide (CO2) was investigated, and trans[Fe(dmpe)2(CO)H] · [HCO3] (5) was identified as a reaction byproduct. Both the carbonyl ligand and the bicarbonate anion are derived from CO2, and this effectively constitutes a disproportionation of CO2 to CO and CO32-. trans-[Fe(dmpe)2(CO)H].[HCO3] (5) was characterized by crystallography and by NMR spectroscopy. © 2008 American Chemical Society.
Original language | English |
---|---|
Pages (from-to) | 3328-3330 |
Number of pages | 3 |
Journal | Organometallics |
Volume | 27 |
Issue number | 14 |
DOIs | |
Publication status | Published - 28 Jul 2008 |