Redox-mediated reactions of vinylferrocene: toward redox auxiliaries

Alan A. Wiles, Xiaolu Zhang, Brian Fitzpatrick, De-Liang Long, Stuart Alan Macgregor, Graeme Cooke

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Chemical redox reactions have been exploited to transformunreactive vinylferrocene into a powerful dienophile for the Diels–Alder reaction and reactive substrate for thiol addition reactionsupon conversion to its ferrocenium state. We have further investigatedthe ability of these reactions to facilitate redox-auxiliary-likereactivity by further hydrogenolyisis of the Diels–Alder adduct tothe corresponding cyclopentane derivative.
Original languageEnglish
Pages (from-to)7220-7225
Number of pages6
JournalDalton Transactions
Volume45
Issue number17
Early online date11 Apr 2016
DOIs
Publication statusPublished - 7 May 2016

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