Redox-Controlled Self-Assembly of Vanadium-Seamed Hexameric Pyrogallol[4]Arene Nanocapsules

Xiangquan Hu, Wenjuan Tian, Yuan Jiao, Steven Paul Kelley, Ping Wang, Scott J. Dalgarno, David A. Atwood, Sisi Feng, Jerry L. Atwood

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

Here we report the controlled self-assembly of vanadium-seamed metal–organic nanocapsules with specific metal oxidation state distributions. Three supramolecular assemblies composed of the same numbers of components including 24 metal centers and six pyrogallol[4]arene ligands were constructed: a VIII24L6 capsule, a mixed-valence VIII18VIV6L6 capsule, and a VIV24L6 capsule. Crystallographic studies of the new capsules reveal their remarkable structural complexity and geometries, while marked differences in metal oxidation state distribution greatly affect the photoelectric conversion properties of these assemblies. This work therefore represents a significant step forward in the construction of intricate metal–organic architectures with tailored structure and functionality.
Original languageEnglish
Pages (from-to)20375-20380
Number of pages6
JournalJournal of the American Chemical Society
Volume145
Issue number37
Early online date6 Sept 2023
DOIs
Publication statusPublished - 20 Sept 2023

Keywords

  • Colloid and Surface Chemistry
  • Biochemistry
  • General Chemistry
  • Catalysis

ASJC Scopus subject areas

  • General Chemistry
  • Biochemistry
  • Catalysis
  • Colloid and Surface Chemistry

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