Reactions of Co-ordinated Ligands. Part 27. Formation of h³-Allyl and s-Vinyl Complexes by Nucleophilic Attack on Cationic Molybdenum Monoacetylene Complexes. Molecular Structures of [Mo(CO)(PEt₃)(h³-anti-1-MeC₃H₄)(h⁵-C₉H₇)] and [Mo{P(OMe)₃}₃{s-(E)-CHCHBu^t}(h-C₅H₅)]

Stephen R. Allen^*, Paul K. Baker, Stephen G. Barnes, Martin Bottrill, Michael Green, A. Guy Orpen, Ian D. Williams, Alan J. Welch

^*Corresponding author for this work

Institute of Chemical Sciences
School of Engineering & Physical Sciences

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Reactions of Co-ordinated Ligands. Part 27. Formation of h³-Allyl and s-Vinyl Complexes by Nucleophilic Attack on Cationic Molybdenum Monoacetylene Complexes. Molecular Structures of [Mo(CO)(PEt₃)(h³-anti-1-MeC₃H₄)(h⁵-C₉H₇)] and [Mo{P(OMe)₃}₃{s-(E)-CHCHBu^t}(h-C₅H₅)]

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INIS

Chemistry

Reactions of Co-ordinated Ligands. Part 27. Formation of h3-Allyl and s-Vinyl Complexes by Nucleophilic Attack on Cationic Molybdenum Monoacetylene Complexes. Molecular Structures of [Mo(CO)(PEt3)(h3-anti-1-MeC3H4)(h5-C9H7)] and [Mo{P(OMe)3}3{s-(E)-CHCHBut}(h-C5H5)]

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INIS

Chemistry

Reactions of Co-ordinated Ligands. Part 27. Formation of h³-Allyl and s-Vinyl Complexes by Nucleophilic Attack on Cationic Molybdenum Monoacetylene Complexes. Molecular Structures of [Mo(CO)(PEt₃)(h³-anti-1-MeC₃H₄)(h⁵-C₉H₇)] and [Mo{P(OMe)₃}₃{s-(E)-CHCHBu^t}(h-C₅H₅)]