Reactions of zero-valent platinum-sulphur dioxide complexes with dienes; isolation and x-ray crystal structure of a novel, μ-phenyl, μ-phosphido-, μ-sulphur dioxide triangulo-triplatinum cluster

David G. Evans; Glyn R. Hughes; D. Michael P. Mingos; Jean Marie Bassett; Alan J. Welch

doi:10.1039/C39800001255

Reactions of zero-valent platinum-sulphur dioxide complexes with dienes; isolation and x-ray crystal structure of a novel, μ-phenyl, μ-phosphido-, μ-sulphur dioxide triangulo-triplatinum cluster

David G. Evans, Glyn R. Hughes, D. Michael P. Mingos^*, Jean Marie Bassett, Alan J. Welch

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

47 Citations (Scopus)

Abstract

The complex Pt(SO₂)₂(PPh₃)₂ reacts with butadiene and isoprene to give the complexes Pt(1,2-η-C ₄H₅R) (SO₂) (PPh₃)₂ (R = H or Me) which, on refluxing in benzene, afford high yields of the triangulo-cluster compound Pt₃(μ-Ph)(μ-PPh₂)(μ- SO₂)(PPh₃)₃, characterised by a single crystal X-ray diffraction study.

Original language	English
Pages (from-to)	1255-1257
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/C39800001255
Publication status	Published - 1980

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39800001255

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Evans, D. G., Hughes, G. R., P. Mingos, D. M., Bassett, J. M., & Welch, A. J. (1980). Reactions of zero-valent platinum-sulphur dioxide complexes with dienes; isolation and x-ray crystal structure of a novel, μ-phenyl, μ-phosphido-, μ-sulphur dioxide triangulo-triplatinum cluster. Journal of the Chemical Society, Chemical Communications, (24), 1255-1257. https://doi.org/10.1039/C39800001255

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title = "Reactions of zero-valent platinum-sulphur dioxide complexes with dienes; isolation and x-ray crystal structure of a novel, μ-phenyl, μ-phosphido-, μ-sulphur dioxide triangulo-triplatinum cluster",

abstract = "The complex Pt(SO2)2(PPh3)2 reacts with butadiene and isoprene to give the complexes Pt(1,2-η-C 4H5R) (SO2) (PPh3)2 (R = H or Me) which, on refluxing in benzene, afford high yields of the triangulo-cluster compound Pt3(μ-Ph)(μ-PPh2)(μ- SO2)(PPh3)3, characterised by a single crystal X-ray diffraction study.",

author = "Evans, {David G.} and Hughes, {Glyn R.} and {P. Mingos}, {D. Michael} and Bassett, {Jean Marie} and Welch, {Alan J.}",

year = "1980",

doi = "10.1039/C39800001255",

language = "English",

pages = "1255--1257",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "24",

}

Evans, DG, Hughes, GR, P. Mingos, DM, Bassett, JM & Welch, AJ 1980, 'Reactions of zero-valent platinum-sulphur dioxide complexes with dienes; isolation and x-ray crystal structure of a novel, μ-phenyl, μ-phosphido-, μ-sulphur dioxide triangulo-triplatinum cluster', Journal of the Chemical Society, Chemical Communications, no. 24, pp. 1255-1257. https://doi.org/10.1039/C39800001255

Reactions of zero-valent platinum-sulphur dioxide complexes with dienes; isolation and x-ray crystal structure of a novel, μ-phenyl, μ-phosphido-, μ-sulphur dioxide triangulo-triplatinum cluster. / Evans, David G.; Hughes, Glyn R.; P. Mingos, D. Michael et al.
In: Journal of the Chemical Society, Chemical Communications, No. 24, 1980, p. 1255-1257.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Reactions of zero-valent platinum-sulphur dioxide complexes with dienes; isolation and x-ray crystal structure of a novel, μ-phenyl, μ-phosphido-, μ-sulphur dioxide triangulo-triplatinum cluster

AU - Evans, David G.

AU - Hughes, Glyn R.

AU - P. Mingos, D. Michael

AU - Bassett, Jean Marie

AU - Welch, Alan J.

PY - 1980

Y1 - 1980

N2 - The complex Pt(SO2)2(PPh3)2 reacts with butadiene and isoprene to give the complexes Pt(1,2-η-C 4H5R) (SO2) (PPh3)2 (R = H or Me) which, on refluxing in benzene, afford high yields of the triangulo-cluster compound Pt3(μ-Ph)(μ-PPh2)(μ- SO2)(PPh3)3, characterised by a single crystal X-ray diffraction study.

AB - The complex Pt(SO2)2(PPh3)2 reacts with butadiene and isoprene to give the complexes Pt(1,2-η-C 4H5R) (SO2) (PPh3)2 (R = H or Me) which, on refluxing in benzene, afford high yields of the triangulo-cluster compound Pt3(μ-Ph)(μ-PPh2)(μ- SO2)(PPh3)3, characterised by a single crystal X-ray diffraction study.

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U2 - 10.1039/C39800001255

DO - 10.1039/C39800001255

M3 - Article

AN - SCOPUS:37049110036

SN - 0022-4936

SP - 1255

EP - 1257

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 24

ER -

Reactions of zero-valent platinum-sulphur dioxide complexes with dienes; isolation and x-ray crystal structure of a novel, μ-phenyl, μ-phosphido-, μ-sulphur dioxide triangulo-triplatinum cluster

Abstract

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