Reactions of thioketones. Part III. Reaction of chloramine T with aliphatic and aromatic thioketones

Malcolm M Campbell, D M Evgenios

Research output: Contribution to journalArticle

Abstract

Chloramine T reacted readily with aliphatic and aromatic thiones, acting as a nucleophilic and as an oxidizing reagent. The non-thioenolizable thiones, thioadamantanone and thiobenzophenone afforded thio-ozonide products. Thiocamphor, however, gave an unsaturated disulphide dimer which on heating underwent a stereospecific Cope-type rearrangement.

Original languageEnglish
Pages (from-to)2866-2869
Number of pages4
JournalJournal of the Chemical Society, Perkin Transactions 1
Publication statusPublished - 1973

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