Abstract
Chloramine T reacted readily with aliphatic and aromatic thiones, acting as a nucleophilic and as an oxidizing reagent. The non-thioenolizable thiones, thioadamantanone and thiobenzophenone afforded thio-ozonide products. Thiocamphor, however, gave an unsaturated disulphide dimer which on heating underwent a stereospecific Cope-type rearrangement.
| Original language | English |
|---|---|
| Pages (from-to) | 2866-2869 |
| Number of pages | 4 |
| Journal | Journal of the Chemical Society, Perkin Transactions 1 |
| Publication status | Published - 1973 |