Chloramine T reacted readily with aliphatic and aromatic thiones, acting as a nucleophilic and as an oxidizing reagent. The non-thioenolizable thiones, thioadamantanone and thiobenzophenone afforded thio-ozonide products. Thiocamphor, however, gave an unsaturated disulphide dimer which on heating underwent a stereospecific Cope-type rearrangement.
|Number of pages||4|
|Journal||Journal of the Chemical Society, Perkin Transactions 1|
|Publication status||Published - 1973|