Reactions of isopropyl radicals in the presence of gaseous caesium

A. U. Chaudhry; B. G. Gowenlock

doi:10.1039/J19690000560

Reactions of isopropyl radicals in the presence of gaseous caesium

A. U. Chaudhry, B. G. Gowenlock

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

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Abstract

Isopropyl radicals are produced by photolysis of 2,2'-azopropane. In the presence of caesium vapour, high values for the disproportionation: combination ratio are observed. The intermediate formation of a caesium alkyl may account for this observation.

Original language	English
Pages (from-to)	560-561
Number of pages	2
Journal	Journal of the Chemical Society A: Inorganic, Physical, Theoretical
DOIs	https://doi.org/10.1039/J19690000560
Publication status	Published - 1969

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title = "Reactions of isopropyl radicals in the presence of gaseous caesium",

abstract = "Isopropyl radicals are produced by photolysis of 2,2'-azopropane. In the presence of caesium vapour, high values for the disproportionation: combination ratio are observed. The intermediate formation of a caesium alkyl may account for this observation.",

author = "Chaudhry, {A. U.} and Gowenlock, {B. G.}",

year = "1969",

doi = "10.1039/J19690000560",

language = "English",

pages = "560--561",

journal = "Journal of the Chemical Society A: Inorganic, Physical, Theoretical",

issn = "0022-4944",

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T1 - Reactions of isopropyl radicals in the presence of gaseous caesium

AU - Chaudhry, A. U.

AU - Gowenlock, B. G.

PY - 1969

Y1 - 1969

N2 - Isopropyl radicals are produced by photolysis of 2,2'-azopropane. In the presence of caesium vapour, high values for the disproportionation: combination ratio are observed. The intermediate formation of a caesium alkyl may account for this observation.

AB - Isopropyl radicals are produced by photolysis of 2,2'-azopropane. In the presence of caesium vapour, high values for the disproportionation: combination ratio are observed. The intermediate formation of a caesium alkyl may account for this observation.

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U2 - 10.1039/J19690000560

DO - 10.1039/J19690000560

M3 - Article

SN - 0022-4944

SP - 560

EP - 561

JO - Journal of the Chemical Society A: Inorganic, Physical, Theoretical

JF - Journal of the Chemical Society A: Inorganic, Physical, Theoretical

ER -

Reactions of isopropyl radicals in the presence of gaseous caesium

Abstract

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