Isopropyl radicals are produced by photolysis of 2,2'-azopropane. In the presence of caesium vapour, high values for the disproportionation: combination ratio are observed. The intermediate formation of a caesium alkyl may account for this observation.
|Number of pages||2|
|Journal||Journal of the Chemical Society A: Inorganic, Physical, Theoretical|
|Publication status||Published - 1969|