Reactions of isopropyl radicals in the presence of gaseous caesium

A. U. Chaudhry, B. G. Gowenlock

Research output: Contribution to journalArticle

Abstract

Isopropyl radicals are produced by photolysis of 2,2'-azopropane. In the presence of caesium vapour, high values for the disproportionation: combination ratio are observed. The intermediate formation of a caesium alkyl may account for this observation.

Original languageEnglish
Pages (from-to)560-561
Number of pages2
JournalJournal of the Chemical Society A: Inorganic, Physical, Theoretical
DOIs
Publication statusPublished - 1969

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Cesium
Photolysis
Vapors

Cite this

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title = "Reactions of isopropyl radicals in the presence of gaseous caesium",
abstract = "Isopropyl radicals are produced by photolysis of 2,2'-azopropane. In the presence of caesium vapour, high values for the disproportionation: combination ratio are observed. The intermediate formation of a caesium alkyl may account for this observation.",
author = "Chaudhry, {A. U.} and Gowenlock, {B. G.}",
year = "1969",
doi = "10.1039/J19690000560",
language = "English",
pages = "560--561",
journal = "Journal of the Chemical Society A: Inorganic, Physical, Theoretical",
issn = "0022-4944",
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Reactions of isopropyl radicals in the presence of gaseous caesium. / Chaudhry, A. U.; Gowenlock, B. G.

In: Journal of the Chemical Society A: Inorganic, Physical, Theoretical, 1969, p. 560-561.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Reactions of isopropyl radicals in the presence of gaseous caesium

AU - Chaudhry, A. U.

AU - Gowenlock, B. G.

PY - 1969

Y1 - 1969

N2 - Isopropyl radicals are produced by photolysis of 2,2'-azopropane. In the presence of caesium vapour, high values for the disproportionation: combination ratio are observed. The intermediate formation of a caesium alkyl may account for this observation.

AB - Isopropyl radicals are produced by photolysis of 2,2'-azopropane. In the presence of caesium vapour, high values for the disproportionation: combination ratio are observed. The intermediate formation of a caesium alkyl may account for this observation.

UR - http://www.scopus.com/inward/record.url?scp=37049115862&partnerID=8YFLogxK

U2 - 10.1039/J19690000560

DO - 10.1039/J19690000560

M3 - Article

SP - 560

EP - 561

JO - Journal of the Chemical Society A: Inorganic, Physical, Theoretical

JF - Journal of the Chemical Society A: Inorganic, Physical, Theoretical

SN - 0022-4944

ER -