Reactions of Co-ordinated Ligands. Part 45. Ligand Displacement and Oxidative Reactions of the Carbyne Complex[Mo(≡C-...CH2But){P(OMe)3}2(η-C5H5)] ; Crystal and Molecular Structures of [Mo{η3-RN=C-C(CH2But)-...C=NR}-(CNR)2(η-C5H5)] (R = 2,6-Me2C6H3), [Mo(C=CHBut)I{P(OMe)3)}2(η-C5H5)], and [Mo{=C(CH2But)P(O)(OMe)2}{P(OMe)3}(η-C5H5)]

Paul K. Baker, Geoffrey K. Barker, Daljit S. Gill, Michael Green, A. Guy Orpen, Ian D. Williams, Alan J. Welch

Research output: Contribution to journalArticle

Original languageEnglish
Pages (from-to)1321-1331
Number of pages11
JournalJournal of the Chemical Society, Dalton Transactions
Issue number7
DOIs
Publication statusPublished - 1989

ASJC Scopus subject areas

  • Chemistry(all)

Fingerprint Dive into the research topics of 'Reactions of Co-ordinated Ligands. Part 45. Ligand Displacement and Oxidative Reactions of the Carbyne Complex[Mo(≡C-...CH<sub>2</sub>Bu<sup>t</sup>){P(OMe)<sub>3</sub>}<sub>2</sub>(η-C<sub>5</sub>H<sub>5</sub>)] ; Crystal and Molecular Structures of [Mo{η<sup>3</sup>-RN=C-C(CH<sub>2</sub>Bu<sup>t</sup>)-...C=NR}-(CNR)<sub>2</sub>(η-C<sub>5</sub>H<sub>5</sub>)] (R = 2,6-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>), [Mo(C=CHBu<sup>t</sup>)I{P(OMe)<sub>3</sub>)}<sub>2</sub>(η-C<sub>5</sub>H<sub>5</sub>)], and [Mo{=C(CH<sub>2</sub>Bu<sup>t</sup>)P(O)(OMe)<sub>2</sub>}{P(OMe)<sub>3</sub>}(η-C<sub>5</sub>H<sub>5</sub>)]'. Together they form a unique fingerprint.

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