Reactions of Co-ordinated Ligands. Part 45. Ligand Displacement and Oxidative Reactions of the Carbyne Complex[Mo(≡C-...CH2But){P(OMe)3}2(η-C5H5)] ; Crystal and Molecular Structures of [Mo{η3-RN=C-C(CH2But)-...C=NR}-(CNR)2(η-C5H5)] (R = 2,6-Me2C6H3), [Mo(C=CHBut)I{P(OMe)3)}2(η-C5H5)], and [Mo{=C(CH2But)P(O)(OMe)2}{P(OMe)3}(η-C5H5)]

Paul K. Baker; Geoffrey K. Barker; Daljit S. Gill; Michael Green; A. Guy Orpen; Ian D. Williams; Alan J. Welch

doi:10.1039/DT9890001321

Reactions of Co-ordinated Ligands. Part 45. Ligand Displacement and Oxidative Reactions of the Carbyne Complex[Mo(≡C-...CH₂Bu^t){P(OMe)₃}₂(η-C₅H₅)] ; Crystal and Molecular Structures of [Mo{η³-RN=C-C(CH₂Bu^t)-...C=NR}-(CNR)₂(η-C₅H₅)] (R = 2,6-Me₂C₆H₃), [Mo(C=CHBu^t)I{P(OMe)₃)}₂(η-C₅H₅)], and [Mo{=C(CH₂Bu^t)P(O)(OMe)₂}{P(OMe)₃}(η-C₅H₅)]

Paul K. Baker, Geoffrey K. Barker, Daljit S. Gill, Michael Green^*, A. Guy Orpen, Ian D. Williams, Alan J. Welch

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Original language	English
Pages (from-to)	1321-1331
Number of pages	11
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	7
DOIs	https://doi.org/10.1039/DT9890001321
Publication status	Published - 1989

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1039/DT9890001321

Cite this

Baker, P. K., Barker, G. K., Gill, D. S., Green, M., Orpen, A. G., Williams, I. D., & Welch, A. J. (1989). Reactions of Co-ordinated Ligands. Part 45. Ligand Displacement and Oxidative Reactions of the Carbyne Complex[Mo(≡C-...CH₂Bu^t){P(OMe)₃}₂(η-C₅H₅)] ; Crystal and Molecular Structures of [Mo{η³-RN=C-C(CH₂Bu^t)-...C=NR}-(CNR)₂(η-C₅H₅)] (R = 2,6-Me₂C₆H₃), [Mo(C=CHBu^t)I{P(OMe)₃)}₂(η-C₅H₅)], and [Mo{=C(CH₂Bu^t)P(O)(OMe)₂}{P(OMe)₃}(η-C₅H₅)]. Journal of the Chemical Society, Dalton Transactions, (7), 1321-1331. https://doi.org/10.1039/DT9890001321

Baker, Paul K. ; Barker, Geoffrey K. ; Gill, Daljit S. et al. / Reactions of Co-ordinated Ligands. Part 45. Ligand Displacement and Oxidative Reactions of the Carbyne Complex[Mo(≡C-...CH₂Bu^t){P(OMe)₃}₂(η-C₅H₅)] ; Crystal and Molecular Structures of [Mo{η³-RN=C-C(CH₂Bu^t)-...C=NR}-(CNR)₂(η-C₅H₅)] (R = 2,6-Me₂C₆H₃), [Mo(C=CHBu^t)I{P(OMe)₃)}₂(η-C₅H₅)], and [Mo{=C(CH₂Bu^t)P(O)(OMe)₂}{P(OMe)₃}(η-C₅H₅)]. In: Journal of the Chemical Society, Dalton Transactions. 1989 ; No. 7. pp. 1321-1331.

@article{06d5976458934576a5409ddba5ccdbb2,

title = "Reactions of Co-ordinated Ligands. Part 45. Ligand Displacement and Oxidative Reactions of the Carbyne Complex[Mo(≡C-...CH2But){P(OMe)3}2(η-C5H5)] ; Crystal and Molecular Structures of [Mo{η3-RN=C-C(CH2But)-...C=NR}-(CNR)2(η-C5H5)] (R = 2,6-Me2C6H3), [Mo(C=CHBut)I{P(OMe)3)}2(η-C5H5)], and [Mo{=C(CH2But)P(O)(OMe)2}{P(OMe)3}(η-C5H5)]",

author = "Baker, {Paul K.} and Barker, {Geoffrey K.} and Gill, {Daljit S.} and Michael Green and Orpen, {A. Guy} and Williams, {Ian D.} and Welch, {Alan J.}",

year = "1989",

doi = "10.1039/DT9890001321",

language = "English",

pages = "1321--1331",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "0300-9246",

number = "7",

}

Baker, PK, Barker, GK, Gill, DS, Green, M, Orpen, AG, Williams, ID & Welch, AJ 1989, 'Reactions of Co-ordinated Ligands. Part 45. Ligand Displacement and Oxidative Reactions of the Carbyne Complex[Mo(≡C-...CH₂Bu^t){P(OMe)₃}₂(η-C₅H₅)] ; Crystal and Molecular Structures of [Mo{η³-RN=C-C(CH₂Bu^t)-...C=NR}-(CNR)₂(η-C₅H₅)] (R = 2,6-Me₂C₆H₃), [Mo(C=CHBu^t)I{P(OMe)₃)}₂(η-C₅H₅)], and [Mo{=C(CH₂Bu^t)P(O)(OMe)₂}{P(OMe)₃}(η-C₅H₅)]', Journal of the Chemical Society, Dalton Transactions, no. 7, pp. 1321-1331. https://doi.org/10.1039/DT9890001321

Reactions of Co-ordinated Ligands. Part 45. Ligand Displacement and Oxidative Reactions of the Carbyne Complex[Mo(≡C-...CH₂Bu^t){P(OMe)₃}₂(η-C₅H₅)] ; Crystal and Molecular Structures of [Mo{η³-RN=C-C(CH₂Bu^t)-...C=NR}-(CNR)₂(η-C₅H₅)] (R = 2,6-Me₂C₆H₃), [Mo(C=CHBu^t)I{P(OMe)₃)}₂(η-C₅H₅)], and [Mo{=C(CH₂Bu^t)P(O)(OMe)₂}{P(OMe)₃}(η-C₅H₅)]. / Baker, Paul K.; Barker, Geoffrey K.; Gill, Daljit S. et al.

In: Journal of the Chemical Society, Dalton Transactions, No. 7, 1989, p. 1321-1331.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Reactions of Co-ordinated Ligands. Part 45. Ligand Displacement and Oxidative Reactions of the Carbyne Complex[Mo(≡C-...CH2But){P(OMe)3}2(η-C5H5)] ; Crystal and Molecular Structures of [Mo{η3-RN=C-C(CH2But)-...C=NR}-(CNR)2(η-C5H5)] (R = 2,6-Me2C6H3), [Mo(C=CHBut)I{P(OMe)3)}2(η-C5H5)], and [Mo{=C(CH2But)P(O)(OMe)2}{P(OMe)3}(η-C5H5)]

AU - Baker, Paul K.

AU - Barker, Geoffrey K.

AU - Gill, Daljit S.

AU - Green, Michael

AU - Orpen, A. Guy

AU - Williams, Ian D.

AU - Welch, Alan J.

PY - 1989

Y1 - 1989

UR - http://www.scopus.com/inward/record.url?scp=51149207855&partnerID=8YFLogxK

U2 - 10.1039/DT9890001321

DO - 10.1039/DT9890001321

M3 - Article

AN - SCOPUS:51149207855

SN - 0300-9246

SP - 1321

EP - 1331

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 7

ER -

Baker PK, Barker GK, Gill DS, Green M, Orpen AG, Williams ID et al. Reactions of Co-ordinated Ligands. Part 45. Ligand Displacement and Oxidative Reactions of the Carbyne Complex[Mo(≡C-...CH₂Bu^t){P(OMe)₃}₂(η-C₅H₅)] ; Crystal and Molecular Structures of [Mo{η³-RN=C-C(CH₂Bu^t)-...C=NR}-(CNR)₂(η-C₅H₅)] (R = 2,6-Me₂C₆H₃), [Mo(C=CHBu^t)I{P(OMe)₃)}₂(η-C₅H₅)], and [Mo{=C(CH₂Bu^t)P(O)(OMe)₂}{P(OMe)₃}(η-C₅H₅)]. Journal of the Chemical Society, Dalton Transactions. 1989;(7):1321-1331. doi: 10.1039/DT9890001321

ASJC Scopus subject areas

Access to Document

Other files and links

Cite this