Reactions of co-ordinated ligands. Part 37. Synthesis and structure of the dimolybdenum µ-allylidene complex [Mo2(µ-σ:η3-CHCHCMe2)(CO)4(η-C5H5)2]; formation and crystal structure of the oxo-µ-allylidene complex [Mo2O(µ-σ:η3-CHCHCMe2)(µ-CO)(CO)(η-C5H5)2]. Thermal rearrangement to alkyne and 1,3-diene dimolybdenum species and structure of [Mo334-CCHCMeCH)(CO)4(η-C5H5)3]

W. Eammon Carroll, Michael Green, A. Guy Orpen, Colin J. Schaverien, Ian D. Williams, Alan J. Welch

Research output: Contribution to journalArticle

Abstract


Original languageEnglish
Pages (from-to)1021-1030
Number of pages10
JournalJournal of the Chemical Society, Dalton Transactions
Issue number5
DOIs
Publication statusPublished - 1986

ASJC Scopus subject areas

  • Chemistry(all)

Fingerprint Dive into the research topics of 'Reactions of co-ordinated ligands. Part 37. Synthesis and structure of the dimolybdenum µ-allylidene complex [Mo<sub>2</sub>(µ-σ:η<sup>3</sup>-CHCHCMe<sub>2</sub>)(CO)<sub>4</sub>(η-C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>]; formation and crystal structure of the oxo-µ-allylidene complex [Mo<sub>2</sub>O(µ-σ:η<sup>3</sup>-CHCHCMe<sub>2</sub>)(µ-CO)(CO)(η-C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>]. Thermal rearrangement to alkyne and 1,3-diene dimolybdenum species and structure of [Mo<sub>3</sub>(µ<sub>3</sub>-η<sup>4</sup>-CCHCMeCH)(CO)<sub>4</sub>(η-C<sub>5</sub>H<sub>5</sub>)<sub>3</sub>]'. Together they form a unique fingerprint.

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