Reactions of co-ordinated ligands. Part 37. Synthesis and structure of the dimolybdenum µ-allylidene complex [Mo2(µ-σ:η3-CHCHCMe2)(CO)4(η-C5H5)2]; formation and crystal structure of the oxo-µ-allylidene complex [Mo2O(µ-σ:η3-CHCHCMe2)(µ-CO)(CO)(η-C5H5)2]. Thermal rearrangement to alkyne and 1,3-diene dimolybdenum species and structure of [Mo3(µ3-η4-CCHCMeCH)(CO)4(η-C5H5)3]

W. Eammon Carroll; Michael Green; A. Guy Orpen; Colin J. Schaverien; Ian D. Williams; Alan J. Welch

doi:10.1039/DT9860001021

Reactions of co-ordinated ligands. Part 37. Synthesis and structure of the dimolybdenum µ-allylidene complex [Mo₂(µ-σ:η³-CHCHCMe₂)(CO)₄(η-C₅H₅)₂]; formation and crystal structure of the oxo-µ-allylidene complex [Mo₂O(µ-σ:η³-CHCHCMe₂)(µ-CO)(CO)(η-C₅H₅)₂]. Thermal rearrangement to alkyne and 1,3-diene dimolybdenum species and structure of [Mo₃(µ₃-η⁴-CCHCMeCH)(CO)₄(η-C₅H₅)₃]

W. Eammon Carroll, Michael Green^*, A. Guy Orpen, Colin J. Schaverien, Ian D. Williams, Alan J. Welch

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

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Abstract

Original language	English
Pages (from-to)	1021-1030
Number of pages	10
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	5
DOIs	https://doi.org/10.1039/DT9860001021
Publication status	Published - 1986

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General Chemistry

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Carroll, W. E., Green, M., Orpen, A. G., Schaverien, C. J., Williams, I. D., & Welch, A. J. (1986). Reactions of co-ordinated ligands. Part 37. Synthesis and structure of the dimolybdenum µ-allylidene complex [Mo₂(µ-σ:η³-CHCHCMe₂)(CO)₄(η-C₅H₅)₂]; formation and crystal structure of the oxo-µ-allylidene complex [Mo₂O(µ-σ:η³-CHCHCMe₂)(µ-CO)(CO)(η-C₅H₅)₂]. Thermal rearrangement to alkyne and 1,3-diene dimolybdenum species and structure of [Mo₃(µ₃-η⁴-CCHCMeCH)(CO)₄(η-C₅H₅)₃]. Journal of the Chemical Society, Dalton Transactions, (5), 1021-1030. https://doi.org/10.1039/DT9860001021

Carroll, W. Eammon ; Green, Michael ; Orpen, A. Guy et al. / Reactions of co-ordinated ligands. Part 37. Synthesis and structure of the dimolybdenum µ-allylidene complex [Mo₂(µ-σ:η³-CHCHCMe₂)(CO)₄(η-C₅H₅)₂]; formation and crystal structure of the oxo-µ-allylidene complex [Mo₂O(µ-σ:η³-CHCHCMe₂)(µ-CO)(CO)(η-C₅H₅)₂]. Thermal rearrangement to alkyne and 1,3-diene dimolybdenum species and structure of [Mo₃(µ₃-η⁴-CCHCMeCH)(CO)₄(η-C₅H₅)₃]. In: Journal of the Chemical Society, Dalton Transactions. 1986 ; No. 5. pp. 1021-1030.

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title = "Reactions of co-ordinated ligands. Part 37. Synthesis and structure of the dimolybdenum µ-allylidene complex [Mo2(µ-σ:η3-CHCHCMe2)(CO)4(η-C5H5)2]; formation and crystal structure of the oxo-µ-allylidene complex [Mo2O(µ-σ:η3-CHCHCMe2)(µ-CO)(CO)(η-C5H5)2]. Thermal rearrangement to alkyne and 1,3-diene dimolybdenum species and structure of [Mo3(µ3-η4-CCHCMeCH)(CO)4(η-C5H5)3]",

author = "Carroll, {W. Eammon} and Michael Green and Orpen, {A. Guy} and Schaverien, {Colin J.} and Williams, {Ian D.} and Welch, {Alan J.}",

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doi = "10.1039/DT9860001021",

language = "English",

pages = "1021--1030",

journal = "Journal of the Chemical Society, Dalton Transactions",

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Carroll, WE, Green, M, Orpen, AG, Schaverien, CJ, Williams, ID & Welch, AJ 1986, 'Reactions of co-ordinated ligands. Part 37. Synthesis and structure of the dimolybdenum µ-allylidene complex [Mo₂(µ-σ:η³-CHCHCMe₂)(CO)₄(η-C₅H₅)₂]; formation and crystal structure of the oxo-µ-allylidene complex [Mo₂O(µ-σ:η³-CHCHCMe₂)(µ-CO)(CO)(η-C₅H₅)₂]. Thermal rearrangement to alkyne and 1,3-diene dimolybdenum species and structure of [Mo₃(µ₃-η⁴-CCHCMeCH)(CO)₄(η-C₅H₅)₃]', Journal of the Chemical Society, Dalton Transactions, no. 5, pp. 1021-1030. https://doi.org/10.1039/DT9860001021

Reactions of co-ordinated ligands. Part 37. Synthesis and structure of the dimolybdenum µ-allylidene complex [Mo₂(µ-σ:η³-CHCHCMe₂)(CO)₄(η-C₅H₅)₂]; formation and crystal structure of the oxo-µ-allylidene complex [Mo₂O(µ-σ:η³-CHCHCMe₂)(µ-CO)(CO)(η-C₅H₅)₂]. Thermal rearrangement to alkyne and 1,3-diene dimolybdenum species and structure of [Mo₃(µ₃-η⁴-CCHCMeCH)(CO)₄(η-C₅H₅)₃]. / Carroll, W. Eammon; Green, Michael; Orpen, A. Guy et al.
In: Journal of the Chemical Society, Dalton Transactions, No. 5, 1986, p. 1021-1030.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Reactions of co-ordinated ligands. Part 37. Synthesis and structure of the dimolybdenum µ-allylidene complex [Mo2(µ-σ:η3-CHCHCMe2)(CO)4(η-C5H5)2]; formation and crystal structure of the oxo-µ-allylidene complex [Mo2O(µ-σ:η3-CHCHCMe2)(µ-CO)(CO)(η-C5H5)2]. Thermal rearrangement to alkyne and 1,3-diene dimolybdenum species and structure of [Mo3(µ3-η4-CCHCMeCH)(CO)4(η-C5H5)3]

AU - Carroll, W. Eammon

AU - Green, Michael

AU - Orpen, A. Guy

AU - Schaverien, Colin J.

AU - Williams, Ian D.

AU - Welch, Alan J.

PY - 1986

Y1 - 1986

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U2 - 10.1039/DT9860001021

DO - 10.1039/DT9860001021

M3 - Article

SN - 1472-7773

SP - 1021

EP - 1030

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 5

ER -

Carroll WE, Green M, Orpen AG, Schaverien CJ, Williams ID, Welch AJ. Reactions of co-ordinated ligands. Part 37. Synthesis and structure of the dimolybdenum µ-allylidene complex [Mo₂(µ-σ:η³-CHCHCMe₂)(CO)₄(η-C₅H₅)₂]; formation and crystal structure of the oxo-µ-allylidene complex [Mo₂O(µ-σ:η³-CHCHCMe₂)(µ-CO)(CO)(η-C₅H₅)₂]. Thermal rearrangement to alkyne and 1,3-diene dimolybdenum species and structure of [Mo₃(µ₃-η⁴-CCHCMeCH)(CO)₄(η-C₅H₅)₃]. Journal of the Chemical Society, Dalton Transactions. 1986;(5):1021-1030. doi: 10.1039/DT9860001021

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