Reactions of co-ordinated ligands. Part 37. Synthesis and structure of the dimolybdenum µ-allylidene complex [Mo2(µ-σ:η3-CHCHCMe2)(CO)4(η-C5H5)2]; formation and crystal structure of the oxo-µ-allylidene complex [Mo2O(µ-σ:η3-CHCHCMe2)(µ-CO)(CO)(η-C5H5)2]. Thermal rearrangement to alkyne and 1,3-diene dimolybdenum species and structure of [Mo334-CCHCMeCH)(CO)4(η-C5H5)3]

W. Eammon Carroll, Michael Green*, A. Guy Orpen, Colin J. Schaverien, Ian D. Williams, Alan J. Welch

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

24 Citations (Scopus)


Original languageEnglish
Pages (from-to)1021-1030
Number of pages10
JournalJournal of the Chemical Society, Dalton Transactions
Issue number5
Publication statusPublished - 1986

ASJC Scopus subject areas

  • Chemistry(all)

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