Reaction of
Zero-valent Cobalt and Iron Species with Seven-atom Carbaboranes; Molecular
Structures of [4-(Et3P)-1,7-Me2-m4,8-{Co(H)(PEt3)2-m(H)-m(PEt3)}-1,4,7-CCoCB5H4]
and [4,4,4-(ButNC)3-1,7-Me2-1,4,7-CFeCB5H5]

Geoffrey K. Barker; Maria P. Garcia; Michael Green; F. Gordon A. Stone; Hans E. Parge; Alan J. Welch

doi:10.1039/C39820000688

Reaction of Zero-valent Cobalt and Iron Species with Seven-atom Carbaboranes; Molecular Structures of [4-(Et₃P)-1,7-Me₂-m_4,8-{Co(H)(PEt₃)₂-m(H)-m(PEt₃)}-1,4,7-CCoCB₅H₄] and [4,4,4-(Bu^tNC)₃-1,7-Me₂-1,4,7-CFeCB₅H₅]

Geoffrey K. Barker^*, Maria P. Garcia, Michael Green, F. Gordon A. Stone, Hans E. Parge, Alan J. Welch

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Reaction of closo-2,4-Me₂-2,4-C₂B₅H ₅ with [Co(PEt₃)₄] affords a novel dicobalthydrido-complex containing a phosphido-bridge, whereas [Fe(CNBu ^t;)₅] reacts to form a mononuclear 8-atom cage, in which the iron atom has a cluster connectivity of five.

Original language	English
Pages (from-to)	688-689
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/C39820000688
Publication status	Published - 1982

ASJC Scopus subject areas

Molecular Medicine

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Barker, G. K., Garcia, M. P., Green, M., Stone, F. G. A., Parge, H. E., & Welch, A. J. (1982). Reaction of Zero-valent Cobalt and Iron Species with Seven-atom Carbaboranes; Molecular Structures of [4-(Et₃P)-1,7-Me₂-m_4,8-{Co(H)(PEt₃)₂-m(H)-m(PEt₃)}-1,4,7-CCoCB₅H₄] and [4,4,4-(Bu^tNC)₃-1,7-Me₂-1,4,7-CFeCB₅H₅]. Journal of the Chemical Society, Chemical Communications, (12), 688-689. https://doi.org/10.1039/C39820000688

@article{4780abb39d434a8ebeca86328b6e3586,

title = "Reaction of Zero-valent Cobalt and Iron Species with Seven-atom Carbaboranes; Molecular Structures of [4-(Et3P)-1,7-Me2-m4,8-{Co(H)(PEt3)2-m(H)-m(PEt3)}-1,4,7-CCoCB5H4] and [4,4,4-(ButNC)3-1,7-Me2-1,4,7-CFeCB5H5]",

abstract = "Reaction of closo-2,4-Me2-2,4-C2B5H 5 with [Co(PEt3)4] affords a novel dicobalthydrido-complex containing a phosphido-bridge, whereas [Fe(CNBu t;)5] reacts to form a mononuclear 8-atom cage, in which the iron atom has a cluster connectivity of five.",

author = "Barker, {Geoffrey K.} and Garcia, {Maria P.} and Michael Green and Stone, {F. Gordon A.} and Parge, {Hans E.} and Welch, {Alan J.}",

year = "1982",

doi = "10.1039/C39820000688",

language = "English",

pages = "688--689",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "12",

}

Barker, GK, Garcia, MP, Green, M, Stone, FGA, Parge, HE & Welch, AJ 1982, 'Reaction of Zero-valent Cobalt and Iron Species with Seven-atom Carbaboranes; Molecular Structures of [4-(Et₃P)-1,7-Me₂-m_4,8-{Co(H)(PEt₃)₂-m(H)-m(PEt₃)}-1,4,7-CCoCB₅H₄] and [4,4,4-(Bu^tNC)₃-1,7-Me₂-1,4,7-CFeCB₅H₅]', Journal of the Chemical Society, Chemical Communications, no. 12, pp. 688-689. https://doi.org/10.1039/C39820000688

Reaction of Zero-valent Cobalt and Iron Species with Seven-atom Carbaboranes; Molecular Structures of [4-(Et₃P)-1,7-Me₂-m_4,8-{Co(H)(PEt₃)₂-m(H)-m(PEt₃)}-1,4,7-CCoCB₅H₄] and [4,4,4-(Bu^tNC)₃-1,7-Me₂-1,4,7-CFeCB₅H₅]. / Barker, Geoffrey K.; Garcia, Maria P.; Green, Michael et al.
In: Journal of the Chemical Society, Chemical Communications, No. 12, 1982, p. 688-689.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Reaction of Zero-valent Cobalt and Iron Species with Seven-atom Carbaboranes; Molecular Structures of [4-(Et3P)-1,7-Me2-m4,8-{Co(H)(PEt3)2-m(H)-m(PEt3)}-1,4,7-CCoCB5H4] and [4,4,4-(ButNC)3-1,7-Me2-1,4,7-CFeCB5H5]

AU - Barker, Geoffrey K.

AU - Garcia, Maria P.

AU - Green, Michael

AU - Stone, F. Gordon A.

AU - Parge, Hans E.

AU - Welch, Alan J.

PY - 1982

Y1 - 1982

N2 - Reaction of closo-2,4-Me2-2,4-C2B5H 5 with [Co(PEt3)4] affords a novel dicobalthydrido-complex containing a phosphido-bridge, whereas [Fe(CNBu t;)5] reacts to form a mononuclear 8-atom cage, in which the iron atom has a cluster connectivity of five.

AB - Reaction of closo-2,4-Me2-2,4-C2B5H 5 with [Co(PEt3)4] affords a novel dicobalthydrido-complex containing a phosphido-bridge, whereas [Fe(CNBu t;)5] reacts to form a mononuclear 8-atom cage, in which the iron atom has a cluster connectivity of five.

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U2 - 10.1039/C39820000688

DO - 10.1039/C39820000688

M3 - Article

SN - 0022-4936

SP - 688

EP - 689

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 12

ER -

Barker GK, Garcia MP, Green M, Stone FGA, Parge HE, Welch AJ. Reaction of Zero-valent Cobalt and Iron Species with Seven-atom Carbaboranes; Molecular Structures of [4-(Et₃P)-1,7-Me₂-m_4,8-{Co(H)(PEt₃)₂-m(H)-m(PEt₃)}-1,4,7-CCoCB₅H₄] and [4,4,4-(Bu^tNC)₃-1,7-Me₂-1,4,7-CFeCB₅H₅]. Journal of the Chemical Society, Chemical Communications. 1982;(12):688-689. doi: 10.1039/C39820000688