Reaction of Zero-valent Cobalt and Iron Species with Seven-atom Carbaboranes; Molecular Structures of [4-(Et3P)-1,7-Me2-m4,8-{Co(H)(PEt3)2-m(H)-m(PEt3)}-1,4,7-CCoCB5H4] and [4,4,4-(ButNC)3-1,7-Me2-1,4,7-CFeCB5H5]

Geoffrey K. Barker, Maria P. Garcia, Michael Green, F. Gordon A. Stone, Hans E. Parge, Alan J. Welch

Research output: Contribution to journalArticle

Abstract

Reaction of closo-2,4-Me2-2,4-C2B5H 5 with [Co(PEt3)4] affords a novel dicobalthydrido-complex containing a phosphido-bridge, whereas [Fe(CNBu t;)5] reacts to form a mononuclear 8-atom cage, in which the iron atom has a cluster connectivity of five.

Original languageEnglish
Pages (from-to)688-689
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number12
DOIs
Publication statusPublished - 1982

ASJC Scopus subject areas

  • Molecular Medicine

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