Reaction of o-fluorolithiobenzene with dicarbonyl(η5-cyclopentadienyl)iodoiron: Single-crystal X-ray structure of [(η5-C5H5)Fe(CO)(C6H 4-2-C(O)-C6H4-2′-C6H 4-2″-F)]-η6-Cr(CO)3, a metalated benzophenone

Ian R. Butler; Udai Gill; Yvon LePage; W. Edward Lindsell; Peter N. Preston

doi:10.1021/om00156a043

Reaction of o-fluorolithiobenzene with dicarbonyl(η⁵-cyclopentadienyl)iodoiron: Single-crystal X-ray structure of [(η⁵-C₅H₅)Fe(CO)(C₆H ₄-2-C(O)-C₆H₄-2′-C₆H ₄-2″-F)]-η⁶-Cr(CO)₃, a metalated benzophenone

Ian R. Butler, Udai Gill, Yvon LePage, W. Edward Lindsell, Peter N. Preston

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The reaction of 3 molar equiv of o-fluorolithiobenzene with dicarbonyl(?⁵-cyclopentadienyl)iodoiron results in an intramolecular cyclization to give the metallacyclic product [(?⁵-C₅H₅)Fe(CO)(C₆H ₄-2-C-(O)-C₆H₄-2'-C₆H ₄-2?-F)]. Characterization was made by derivatization with tris(acetonitrile)tricarbonylchromium to give [(?⁵-C₅H₅)Fe(CO)(C₆H ₄-2-C(O)-C₆H₄-2'-C₆H ₄-2?-F)]-?⁶-Cr(CO)₃ (3a). Compound 3a crystallizes in the monoclinic space group P2₁/c with lattice parameters a = 7.1633 (18) Å, b = 13.669 (6) Å, c = 24.116 (3) Å, ß = 95.763 (3)°, V = 2349.33 (12) Å³, ?(calc) = 1.584 g cm^-3, and Z = 4. Least-squares refinement gave a final R_F value of 0.065 for 1864 (I > 2.5s(I)) of 3071 unique reflections (R_w = 0.036, GOF = 2.08). © 1990 American Chemical Society.

Original language	English
Pages (from-to)	1964-1970
Number of pages	7
Journal	Organometallics
Volume	9
Issue number	6
DOIs	https://doi.org/10.1021/om00156a043
Publication status	Published - 1990

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@article{8c1103e1d97e4aa5a21b900f308c522d,

title = "Reaction of o-fluorolithiobenzene with dicarbonyl(η5-cyclopentadienyl)iodoiron: Single-crystal X-ray structure of [(η5-C5H5)Fe(CO)(C6H 4-2-C(O)-C6H4-2′-C6H 4-2″-F)]-η6-Cr(CO)3, a metalated benzophenone",

abstract = "The reaction of 3 molar equiv of o-fluorolithiobenzene with dicarbonyl(?5-cyclopentadienyl)iodoiron results in an intramolecular cyclization to give the metallacyclic product [(?5-C5H5)Fe(CO)(C6H 4-2-C-(O)-C6H4-2'-C6H 4-2?-F)]. Characterization was made by derivatization with tris(acetonitrile)tricarbonylchromium to give [(?5-C5H5)Fe(CO)(C6H 4-2-C(O)-C6H4-2'-C6H 4-2?-F)]-?6-Cr(CO)3 (3a). Compound 3a crystallizes in the monoclinic space group P21/c with lattice parameters a = 7.1633 (18) {\AA}, b = 13.669 (6) {\AA}, c = 24.116 (3) {\AA}, {\ss} = 95.763 (3)°, V = 2349.33 (12) {\AA}3, ?(calc) = 1.584 g cm-3, and Z = 4. Least-squares refinement gave a final RF value of 0.065 for 1864 (I > 2.5s(I)) of 3071 unique reflections (Rw = 0.036, GOF = 2.08). {\textcopyright} 1990 American Chemical Society.",

author = "Butler, {Ian R.} and Udai Gill and Yvon LePage and {Edward Lindsell}, W. and Preston, {Peter N.}",

year = "1990",

doi = "10.1021/om00156a043",

language = "English",

volume = "9",

pages = "1964--1970",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "6",

}

Reaction of o-fluorolithiobenzene with dicarbonyl(η⁵-cyclopentadienyl)iodoiron: Single-crystal X-ray structure of [(η⁵-C₅H₅)Fe(CO)(C₆H ₄-2-C(O)-C₆H₄-2′-C₆H ₄-2″-F)]-η⁶-Cr(CO)₃, a metalated benzophenone. / Butler, Ian R.; Gill, Udai; LePage, Yvon et al.
In: Organometallics, Vol. 9, No. 6, 1990, p. 1964-1970.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Reaction of o-fluorolithiobenzene with dicarbonyl(η5-cyclopentadienyl)iodoiron

T2 - Single-crystal X-ray structure of [(η5-C5H5)Fe(CO)(C6H 4-2-C(O)-C6H4-2′-C6H 4-2″-F)]-η6-Cr(CO)3, a metalated benzophenone

AU - Butler, Ian R.

AU - Gill, Udai

AU - LePage, Yvon

AU - Edward Lindsell, W.

AU - Preston, Peter N.

PY - 1990

Y1 - 1990

N2 - The reaction of 3 molar equiv of o-fluorolithiobenzene with dicarbonyl(?5-cyclopentadienyl)iodoiron results in an intramolecular cyclization to give the metallacyclic product [(?5-C5H5)Fe(CO)(C6H 4-2-C-(O)-C6H4-2'-C6H 4-2?-F)]. Characterization was made by derivatization with tris(acetonitrile)tricarbonylchromium to give [(?5-C5H5)Fe(CO)(C6H 4-2-C(O)-C6H4-2'-C6H 4-2?-F)]-?6-Cr(CO)3 (3a). Compound 3a crystallizes in the monoclinic space group P21/c with lattice parameters a = 7.1633 (18) Å, b = 13.669 (6) Å, c = 24.116 (3) Å, ß = 95.763 (3)°, V = 2349.33 (12) Å3, ?(calc) = 1.584 g cm-3, and Z = 4. Least-squares refinement gave a final RF value of 0.065 for 1864 (I > 2.5s(I)) of 3071 unique reflections (Rw = 0.036, GOF = 2.08). © 1990 American Chemical Society.

AB - The reaction of 3 molar equiv of o-fluorolithiobenzene with dicarbonyl(?5-cyclopentadienyl)iodoiron results in an intramolecular cyclization to give the metallacyclic product [(?5-C5H5)Fe(CO)(C6H 4-2-C-(O)-C6H4-2'-C6H 4-2?-F)]. Characterization was made by derivatization with tris(acetonitrile)tricarbonylchromium to give [(?5-C5H5)Fe(CO)(C6H 4-2-C(O)-C6H4-2'-C6H 4-2?-F)]-?6-Cr(CO)3 (3a). Compound 3a crystallizes in the monoclinic space group P21/c with lattice parameters a = 7.1633 (18) Å, b = 13.669 (6) Å, c = 24.116 (3) Å, ß = 95.763 (3)°, V = 2349.33 (12) Å3, ?(calc) = 1.584 g cm-3, and Z = 4. Least-squares refinement gave a final RF value of 0.065 for 1864 (I > 2.5s(I)) of 3071 unique reflections (Rw = 0.036, GOF = 2.08). © 1990 American Chemical Society.

UR - http://www.scopus.com/inward/record.url?scp=0001229995&partnerID=8YFLogxK

U2 - 10.1021/om00156a043

DO - 10.1021/om00156a043

M3 - Article

SN - 0276-7333

VL - 9

SP - 1964

EP - 1970

JO - Organometallics

JF - Organometallics

IS - 6