Reaction of Bis(triethylphosphine)platinum and Pentakis(t-butyl isocyanide)-ruthenium with Dicarba-nido-hexaboranes(8):  Molecular Structures of [nido-μ4,5-{trans-(Et3P)2Pt(H)}-μ 5,6-H-2,3-C2B4H6], [closo-1,1-(Et3P)2-2,3-Me2-1,2,3-PtC2B4H4] and [RuH(ButNC)5]+[nido-2,3-Me2-C2B4H5]–

Geoffrey K. Barker; Michael Green; Thomas P. Onak; F. Gordon A. Stone; Charles B. Ungermann; Alan J. Welch

doi:10.1039/C39780000169

Reaction of Bis(triethylphosphine)platinum and Pentakis(t-butyl isocyanide)-ruthenium with Dicarba-nido-hexaboranes(8): Molecular Structures of [nido-μ_4,5-{trans-(Et₃P)₂Pt(H)}-μ _5,6-H-2,3-C₂B₄H₆], [closo-1,1-(Et₃P)₂-2,3-Me₂-1,2,3-PtC₂B₄H₄] and [RuH(Bu^tNC)₅]⁺[nido-2,3-Me₂-C₂B₄H₅]–

Geoffrey K. Barker, Michael Green, Thomas P. Onak, F. Gordon A. Stone^*, Charles B. Ungermann, Alan J. Welch

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Reaction of bis(triethylphosphine)platinum and pentakis(t-butyl isocyanide)ruthenium with dicarba-nido-hexaboranes(8): Molecular structures of [nido-μ_4,5-{trans-(Et₃P)₂Pt(H)} -μ_5,6-H-2,3-C₂B₄H₆], [closo-1,1-(Et₃P)₂-2,3-Me₂-1,2,3-PtC ₂B₄H₄], and [RuH(Bu^tNC) ₅]⁺ [nido-2,3-Me₂-2,3-C₂B ₄H₅]^- Reaction of [Pt(PEt₃)₂] with nido-2,3-C ₂B₄H₈ or nido-2,3-Me₂-2,3-C ₂B₄H₆ affords, respectively, [nido-μ_4,5-{trans-(Et₃P)₂Pt(H)} -μ_5,6-H-2,3-C₂B₄H₆] and [nido-μ_4,5-{trans-(Et₃P)₂Pt(H)} -μ_5,6-H-2,3-Me₂-2,3-C₂B₄H ₄], which on pyrolysis yield closo-platinacarbaboranes with nonadjacent and adjacent carbon atoms respectively; in contrast [Ru(Bu ^tNC)₅] reacts with nido-2,3-Me₂-2,3-C ₂B₄H₆ to give[RuH(Bu^tNC) ₅]⁺[nido-2,3-Me₂-2,3-C₂B ₄H₅]^-.

Original language	English
Pages (from-to)	169-171
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/C39780000169
Publication status	Published - 1978

ASJC Scopus subject areas

Molecular Medicine

Access to Document

10.1039/C39780000169

Fingerprint

Dive into the research topics of 'Reaction of Bis(triethylphosphine)platinum and Pentakis(t-butyl isocyanide)-ruthenium with Dicarba-nido-hexaboranes(8): Molecular Structures of [nido-μ_4,5-{trans-(Et₃P)₂Pt(H)}-μ _5,6-H-2,3-C₂B₄H₆], [closo-1,1-(Et₃P)₂-2,3-Me₂-1,2,3-PtC₂B₄H₄] and [RuH(Bu^tNC)₅]⁺[nido-2,3-Me₂-C₂B₄H₅]–'. Together they form a unique fingerprint.

Cite this

Barker, G. K., Green, M., Onak, T. P., Stone, F. G. A., Ungermann, C. B., & Welch, A. J. (1978). Reaction of Bis(triethylphosphine)platinum and Pentakis(t-butyl isocyanide)-ruthenium with Dicarba-nido-hexaboranes(8): Molecular Structures of [nido-μ_4,5-{trans-(Et₃P)₂Pt(H)}-μ _5,6-H-2,3-C₂B₄H₆], [closo-1,1-(Et₃P)₂-2,3-Me₂-1,2,3-PtC₂B₄H₄] and [RuH(Bu^tNC)₅]⁺[nido-2,3-Me₂-C₂B₄H₅]–. Journal of the Chemical Society, Chemical Communications, (4), 169-171. https://doi.org/10.1039/C39780000169

Barker, Geoffrey K. ; Green, Michael ; Onak, Thomas P. et al. / Reaction of Bis(triethylphosphine)platinum and Pentakis(t-butyl isocyanide)-ruthenium with Dicarba-nido-hexaboranes(8): Molecular Structures of [nido-μ_4,5-{trans-(Et₃P)₂Pt(H)}-μ _5,6-H-2,3-C₂B₄H₆], [closo-1,1-(Et₃P)₂-2,3-Me₂-1,2,3-PtC₂B₄H₄] and [RuH(Bu^tNC)₅]⁺[nido-2,3-Me₂-C₂B₄H₅]–. In: Journal of the Chemical Society, Chemical Communications. 1978 ; No. 4. pp. 169-171.

@article{c6726f4779ef4ae397ac16fcf434e0c5,

title = "Reaction of Bis(triethylphosphine)platinum and Pentakis(t-butyl isocyanide)-ruthenium with Dicarba-nido-hexaboranes(8): Molecular Structures of [nido-μ4,5-{trans-(Et3P)2Pt(H)}-μ 5,6-H-2,3-C2B4H6], [closo-1,1-(Et3P)2-2,3-Me2-1,2,3-PtC2B4H4] and [RuH(ButNC)5]+[nido-2,3-Me2-C2B4H5]–",

abstract = "Reaction of bis(triethylphosphine)platinum and pentakis(t-butyl isocyanide)ruthenium with dicarba-nido-hexaboranes(8): Molecular structures of [nido-μ4,5-{trans-(Et3P)2Pt(H)} -μ5,6-H-2,3-C2B4H6], [closo-1,1-(Et3P)2-2,3-Me2-1,2,3-PtC 2B4H4], and [RuH(ButNC) 5]+ [nido-2,3-Me2-2,3-C2B 4H5]- Reaction of [Pt(PEt3)2] with nido-2,3-C 2B4H8 or nido-2,3-Me2-2,3-C 2B4H6 affords, respectively, [nido-μ4,5-{trans-(Et3P)2Pt(H)} -μ5,6-H-2,3-C2B4H6] and [nido-μ4,5-{trans-(Et3P)2Pt(H)} -μ5,6-H-2,3-Me2-2,3-C2B4H 4], which on pyrolysis yield closo-platinacarbaboranes with nonadjacent and adjacent carbon atoms respectively; in contrast [Ru(Bu tNC)5] reacts with nido-2,3-Me2-2,3-C 2B4H6 to give[RuH(ButNC) 5]+[nido-2,3-Me2-2,3-C2B 4H5]-.",

author = "Barker, {Geoffrey K.} and Michael Green and Onak, {Thomas P.} and Stone, {F. Gordon A.} and Ungermann, {Charles B.} and Welch, {Alan J.}",

year = "1978",

doi = "10.1039/C39780000169",

language = "English",

pages = "169--171",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "4",

}

Barker, GK, Green, M, Onak, TP, Stone, FGA, Ungermann, CB & Welch, AJ 1978, 'Reaction of Bis(triethylphosphine)platinum and Pentakis(t-butyl isocyanide)-ruthenium with Dicarba-nido-hexaboranes(8): Molecular Structures of [nido-μ_4,5-{trans-(Et₃P)₂Pt(H)}-μ _5,6-H-2,3-C₂B₄H₆], [closo-1,1-(Et₃P)₂-2,3-Me₂-1,2,3-PtC₂B₄H₄] and [RuH(Bu^tNC)₅]⁺[nido-2,3-Me₂-C₂B₄H₅]–', Journal of the Chemical Society, Chemical Communications, no. 4, pp. 169-171. https://doi.org/10.1039/C39780000169

Reaction of Bis(triethylphosphine)platinum and Pentakis(t-butyl isocyanide)-ruthenium with Dicarba-nido-hexaboranes(8): Molecular Structures of [nido-μ_4,5-{trans-(Et₃P)₂Pt(H)}-μ _5,6-H-2,3-C₂B₄H₆], [closo-1,1-(Et₃P)₂-2,3-Me₂-1,2,3-PtC₂B₄H₄] and [RuH(Bu^tNC)₅]⁺[nido-2,3-Me₂-C₂B₄H₅]–. / Barker, Geoffrey K.; Green, Michael; Onak, Thomas P. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 4, 1978, p. 169-171.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Reaction of Bis(triethylphosphine)platinum and Pentakis(t-butyl isocyanide)-ruthenium with Dicarba-nido-hexaboranes(8): Molecular Structures of [nido-μ4,5-{trans-(Et3P)2Pt(H)}-μ 5,6-H-2,3-C2B4H6], [closo-1,1-(Et3P)2-2,3-Me2-1,2,3-PtC2B4H4] and [RuH(ButNC)5]+[nido-2,3-Me2-C2B4H5]–

AU - Barker, Geoffrey K.

AU - Green, Michael

AU - Onak, Thomas P.

AU - Stone, F. Gordon A.

AU - Ungermann, Charles B.

AU - Welch, Alan J.

PY - 1978

Y1 - 1978

N2 - Reaction of bis(triethylphosphine)platinum and pentakis(t-butyl isocyanide)ruthenium with dicarba-nido-hexaboranes(8): Molecular structures of [nido-μ4,5-{trans-(Et3P)2Pt(H)} -μ5,6-H-2,3-C2B4H6], [closo-1,1-(Et3P)2-2,3-Me2-1,2,3-PtC 2B4H4], and [RuH(ButNC) 5]+ [nido-2,3-Me2-2,3-C2B 4H5]- Reaction of [Pt(PEt3)2] with nido-2,3-C 2B4H8 or nido-2,3-Me2-2,3-C 2B4H6 affords, respectively, [nido-μ4,5-{trans-(Et3P)2Pt(H)} -μ5,6-H-2,3-C2B4H6] and [nido-μ4,5-{trans-(Et3P)2Pt(H)} -μ5,6-H-2,3-Me2-2,3-C2B4H 4], which on pyrolysis yield closo-platinacarbaboranes with nonadjacent and adjacent carbon atoms respectively; in contrast [Ru(Bu tNC)5] reacts with nido-2,3-Me2-2,3-C 2B4H6 to give[RuH(ButNC) 5]+[nido-2,3-Me2-2,3-C2B 4H5]-.

AB - Reaction of bis(triethylphosphine)platinum and pentakis(t-butyl isocyanide)ruthenium with dicarba-nido-hexaboranes(8): Molecular structures of [nido-μ4,5-{trans-(Et3P)2Pt(H)} -μ5,6-H-2,3-C2B4H6], [closo-1,1-(Et3P)2-2,3-Me2-1,2,3-PtC 2B4H4], and [RuH(ButNC) 5]+ [nido-2,3-Me2-2,3-C2B 4H5]- Reaction of [Pt(PEt3)2] with nido-2,3-C 2B4H8 or nido-2,3-Me2-2,3-C 2B4H6 affords, respectively, [nido-μ4,5-{trans-(Et3P)2Pt(H)} -μ5,6-H-2,3-C2B4H6] and [nido-μ4,5-{trans-(Et3P)2Pt(H)} -μ5,6-H-2,3-Me2-2,3-C2B4H 4], which on pyrolysis yield closo-platinacarbaboranes with nonadjacent and adjacent carbon atoms respectively; in contrast [Ru(Bu tNC)5] reacts with nido-2,3-Me2-2,3-C 2B4H6 to give[RuH(ButNC) 5]+[nido-2,3-Me2-2,3-C2B 4H5]-.

UR - http://www.scopus.com/inward/record.url?scp=51149204735&partnerID=8YFLogxK

U2 - 10.1039/C39780000169

DO - 10.1039/C39780000169

M3 - Article

SN - 0022-4936

SP - 169

EP - 171

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 4

ER -

Barker GK, Green M, Onak TP, Stone FGA, Ungermann CB, Welch AJ. Reaction of Bis(triethylphosphine)platinum and Pentakis(t-butyl isocyanide)-ruthenium with Dicarba-nido-hexaboranes(8): Molecular Structures of [nido-μ_4,5-{trans-(Et₃P)₂Pt(H)}-μ _5,6-H-2,3-C₂B₄H₆], [closo-1,1-(Et₃P)₂-2,3-Me₂-1,2,3-PtC₂B₄H₄] and [RuH(Bu^tNC)₅]⁺[nido-2,3-Me₂-C₂B₄H₅]–. Journal of the Chemical Society, Chemical Communications. 1978;(4):169-171. doi: 10.1039/C39780000169

Reaction of Bis(triethylphosphine)platinum and Pentakis(t-butyl isocyanide)-ruthenium with Dicarba-nido-hexaboranes(8): Molecular Structures of [nido-μ4,5-{trans-(Et3P)2Pt(H)}-μ 5,6-H-2,3-C2B4H6], [closo-1,1-(Et3P)2-2,3-Me2-1,2,3-PtC2B4H4] and [RuH(ButNC)5]+[nido-2,3-Me2-C2B4H5]–

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this