Pyridine Directed Assembly of Di-O-Alkyl-tris-p-Carboxylatocalix[4]arenes

Stuart Kennedy; India E. Dodgson; Christine M. Beavers; Simon J. Teat; Scott J. Dalgarno

doi:10.1021/cg200887d

Pyridine Directed Assembly of Di-O-Alkyl-tris-p-Carboxylatocalix[4]arenes

Stuart Kennedy, India E. Dodgson, Christine M. Beavers, Simon J. Teat, Scott J. Dalgarno

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19 Citations (Scopus)

Abstract

Crystallization of four di-O-alkyl-tris-p-carboxylatocalix[4]arenes from a series of pyridine derivatives has been carried out to investigate the effect of introducing alkyl groups around the pyridine guest/template. Where single crystals were obtained, for 12 of 24 possible structures, in all but one case the calixarenes assemble with the pyridine derivative into hydrogen-bonded head-to-head dimers within extended bilayer or nanotubular arrays.

Original language	English
Pages (from-to)	688-697
Number of pages	10
Journal	Crystal Growth and Design
Volume	12
Issue number	2
DOIs	https://doi.org/10.1021/cg200887d
Publication status	Published - 1 Feb 2012

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abstract = "Crystallization of four di-O-alkyl-tris-p-carboxylatocalix[4]arenes from a series of pyridine derivatives has been carried out to investigate the effect of introducing alkyl groups around the pyridine guest/template. Where single crystals were obtained, for 12 of 24 possible structures, in all but one case the calixarenes assemble with the pyridine derivative into hydrogen-bonded head-to-head dimers within extended bilayer or nanotubular arrays.",

author = "Stuart Kennedy and Dodgson, {India E.} and Beavers, {Christine M.} and Teat, {Simon J.} and Dalgarno, {Scott J.}",

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AU - Teat, Simon J.

AU - Dalgarno, Scott J.

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N2 - Crystallization of four di-O-alkyl-tris-p-carboxylatocalix[4]arenes from a series of pyridine derivatives has been carried out to investigate the effect of introducing alkyl groups around the pyridine guest/template. Where single crystals were obtained, for 12 of 24 possible structures, in all but one case the calixarenes assemble with the pyridine derivative into hydrogen-bonded head-to-head dimers within extended bilayer or nanotubular arrays.

AB - Crystallization of four di-O-alkyl-tris-p-carboxylatocalix[4]arenes from a series of pyridine derivatives has been carried out to investigate the effect of introducing alkyl groups around the pyridine guest/template. Where single crystals were obtained, for 12 of 24 possible structures, in all but one case the calixarenes assemble with the pyridine derivative into hydrogen-bonded head-to-head dimers within extended bilayer or nanotubular arrays.

U2 - 10.1021/cg200887d

DO - 10.1021/cg200887d

M3 - Article

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JO - Crystal Growth and Design

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ER -

Pyridine Directed Assembly of Di-O-Alkyl-tris-p-Carboxylatocalix[4]arenes

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